N-[Bis(dimethylamino)methylidene]-2-[(triphenylmethyl)sulfanyl]ethanaminium hexafluorophosphate
The molecular structure of the title compound, C26H32N3S+·PF6−, shows a protonated guanidyl group bridged by an ethylene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—Cgua bonds. The N&#8...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811014929 |
| Summary: | The molecular structure of the title compound, C26H32N3S+·PF6−, shows a protonated guanidyl group bridged by an ethylene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—Cgua bonds. The N—C—C—S group shows a folded nonplanar conformation with a torsion angle of 158.4 (1)°. In the crystal, the cation and anion are linked by an N—H...F interaction. |
|---|---|
| ISSN: | 1600-5368 |