Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity

The aim of the present study was to create a functional, enriched in polyphenols and free of alcohol product obtained by acetic fermentation of beer. Beer and vinegar were tested first for their phenolic content and antioxidant activity, by the Folin Ciocalteu and the free radical scavenging activit...

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Main Authors: Mudura Elena, Coldea Teodora Emilia, Socaciu Carmen, Ranga Floricuţa, Pop Carmen Rodica, Rotar Ancuţa Mihaela, Pasqualone Antonella
Format: Article
Language:English
Published: Serbian Chemical Society 2018-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2018/0352-51391700107M.pdf
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author Mudura Elena
Coldea Teodora Emilia
Socaciu Carmen
Ranga Floricuţa
Pop Carmen Rodica
Rotar Ancuţa Mihaela
Pasqualone Antonella
author_facet Mudura Elena
Coldea Teodora Emilia
Socaciu Carmen
Ranga Floricuţa
Pop Carmen Rodica
Rotar Ancuţa Mihaela
Pasqualone Antonella
author_sort Mudura Elena
collection DOAJ
description The aim of the present study was to create a functional, enriched in polyphenols and free of alcohol product obtained by acetic fermentation of beer. Beer and vinegar were tested first for their phenolic content and antioxidant activity, by the Folin Ciocalteu and the free radical scavenging activity by the 1,1-diphenyl-2-picrylhydrazyl free-radical scavenging assay, respectively. Then, the separation and identification of the 30 phenolic compounds was realized by high-performance liquid chromatography coupled with positive electrospray ionisation and diode array detection (HPLC-DAD–ESI(+)-MS) analysis. Identification of the phenolic compounds data was realized based on the UV spectra of each compound. Based on a calibration curve (R2 = 0.9985), the amounts of the phenolic compounds, expressed as mg cathechin equivalents (CE)/L, were calculated. The total phenolic content of the beer and vinegar samples determined using Folin–Ciocalteu reagent were of 428.9±1.58 and 661.5±7.69 mg GAE L-1, respectively, which contributed to the high antioxidant activity in the vinegar sample of 82.18 %. Statistically significant differences were observed after acetic fermentation between each parameter (p < 0.05). Brown beer vinegar represents a rich source of polyphenols and phenolic derivatives, compared to beer. By its increased phenolic content and antioxidant activity, brown beer vinegar could be considered another source of valuable compounds to beer, which could also be of interest in special diets.
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spelling doaj.art-fcbd5c7b947740249f894beac30d2e582022-12-22T01:37:48ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212018-01-01831193010.2298/JSC170803107M0352-51391700107MBrown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activityMudura Elena0Coldea Teodora Emilia1Socaciu Carmen2Ranga Floricuţa3Pop Carmen Rodica4Rotar Ancuţa Mihaela5Pasqualone Antonella6University of Agricultural Sciences and Veterinary Medicine, Department of Food Engineering, Cluj-Napoca, RomaniaUniversity of Agricultural Sciences and Veterinary Medicine, Department of Food Engineering, Cluj-Napoca, RomaniaUniversity of Agricultural Sciences and Veterinary Medicine, Department of Food Science, Cluj-Napoca, RomaniaUniversity of Agricultural Sciences and Veterinary Medicine, Department of Food Science, Cluj-Napoca, RomaniaUniversity of Agricultural Sciences and Veterinary Medicine, Department of Food Science, Cluj-Napoca, RomaniaUniversity of Agricultural Sciences and Veterinary Medicine, Department of Food Science, Cluj-Napoca, RomaniaFood Science and Technology Unit, Department of Soil, Plant, and Food Science (Di.S.S.P.A.), University of Bari ‘Aldo Moro’, Bari, ItalyThe aim of the present study was to create a functional, enriched in polyphenols and free of alcohol product obtained by acetic fermentation of beer. Beer and vinegar were tested first for their phenolic content and antioxidant activity, by the Folin Ciocalteu and the free radical scavenging activity by the 1,1-diphenyl-2-picrylhydrazyl free-radical scavenging assay, respectively. Then, the separation and identification of the 30 phenolic compounds was realized by high-performance liquid chromatography coupled with positive electrospray ionisation and diode array detection (HPLC-DAD–ESI(+)-MS) analysis. Identification of the phenolic compounds data was realized based on the UV spectra of each compound. Based on a calibration curve (R2 = 0.9985), the amounts of the phenolic compounds, expressed as mg cathechin equivalents (CE)/L, were calculated. The total phenolic content of the beer and vinegar samples determined using Folin–Ciocalteu reagent were of 428.9±1.58 and 661.5±7.69 mg GAE L-1, respectively, which contributed to the high antioxidant activity in the vinegar sample of 82.18 %. Statistically significant differences were observed after acetic fermentation between each parameter (p < 0.05). Brown beer vinegar represents a rich source of polyphenols and phenolic derivatives, compared to beer. By its increased phenolic content and antioxidant activity, brown beer vinegar could be considered another source of valuable compounds to beer, which could also be of interest in special diets.http://www.doiserbia.nb.rs/img/doi/0352-5139/2018/0352-51391700107M.pdfbrewingacetic fermentationpolyphenols quantification
spellingShingle Mudura Elena
Coldea Teodora Emilia
Socaciu Carmen
Ranga Floricuţa
Pop Carmen Rodica
Rotar Ancuţa Mihaela
Pasqualone Antonella
Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
Journal of the Serbian Chemical Society
brewing
acetic fermentation
polyphenols quantification
title Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
title_full Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
title_fullStr Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
title_full_unstemmed Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
title_short Brown beer vinegar: A potentially functional product based on its phenolic profile and antioxidant activity
title_sort brown beer vinegar a potentially functional product based on its phenolic profile and antioxidant activity
topic brewing
acetic fermentation
polyphenols quantification
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2018/0352-51391700107M.pdf
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