Zeta Potential of Beta Zeolites: Influence of Structure, Acidity, pH, Temperature and Concentration

Measurements of the zeta potential of solid heterogeneous supports are important for preparation of metal supported catalysts and for shaping zeolites into extrudates. In the current work, different types of heterogeneous support materials such as SiO2, Al2O3, and a range of beta zeolites of differe...

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Bibliographic Details
Main Authors: Xuan Liu, Päivi Mäki-Arvela, Atte Aho, Zuzana Vajglova, Vladimir M. Gun’ko, Ivo Heinmaa, Narendra Kumar, Kari Eränen, Tapio Salmi, Dmitry Yu. Murzin
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/23/4/946
Description
Summary:Measurements of the zeta potential of solid heterogeneous supports are important for preparation of metal supported catalysts and for shaping zeolites into extrudates. In the current work, different types of heterogeneous support materials such as SiO2, Al2O3, and a range of beta zeolites of different silica- to-alumina ratio were analysed. It was observed that parameters such as temperature, pH and acidity significantly affect the zeta potential. In several instances, depending on the materials’ acidity and microstructure, maxima in zeta potential were observed. The solid materials were thoroughly characterized using XRD, SEM, EDX, TEM, nitrogen physisorption, Al-NMR and FTIR with pyridine before zeta potential measurements.
ISSN:1420-3049