Dynamic Modeling of Fouling in Reverse Osmosis Membranes

During reverse osmosis (RO) membrane filtration, performance is dramatically affected by fouling, which concurrently decreases the permeate flux while increasing the energy required to operate the system. Comprehensive design and optimization of RO systems are best served by an understanding of the...

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Main Authors: Bowen Ling, Peng Xie, David Ladner, Ilenia Battiato
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/11/5/349
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author Bowen Ling
Peng Xie
David Ladner
Ilenia Battiato
author_facet Bowen Ling
Peng Xie
David Ladner
Ilenia Battiato
author_sort Bowen Ling
collection DOAJ
description During reverse osmosis (RO) membrane filtration, performance is dramatically affected by fouling, which concurrently decreases the permeate flux while increasing the energy required to operate the system. Comprehensive design and optimization of RO systems are best served by an understanding of the coupling between membrane shape, local flow field, and fouling; however, current studies focus exclusively on simplified steady-state models that ignore the dynamic coupling between fluid flow, solute transport, and foulant accumulation. We developed a customized solver (SUMs: Stanford University Membrane Solver) under the open source finite volume simulator OpenFOAM to solve transient Navier–Stokes, advection–diffusion, and adsorption–desorption equations for foulant accumulation. We implemented two permeate flux reduction models at the membrane boundary: the resistance-in-series (RIS) model and the effective-pressure-drop (EPD) model. The two models were validated against filtration experiments by comparing the equilibrium flux, pressure drop, and fouling pattern on the membrane. Both models not only predict macroscopic quantities (e.g., permeate flux and pressure drop) but also the fouling pattern developed on the membrane, with a good match with experimental results. Furthermore, the models capture the temporal evolution of foulant accumulation and its coupling with flux reduction.
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spelling doaj.art-fcdd7217361948a1b745cfc4d07edafa2023-11-21T18:57:04ZengMDPI AGMembranes2077-03752021-05-0111534910.3390/membranes11050349Dynamic Modeling of Fouling in Reverse Osmosis MembranesBowen Ling0Peng Xie1David Ladner2Ilenia Battiato3Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaDuring reverse osmosis (RO) membrane filtration, performance is dramatically affected by fouling, which concurrently decreases the permeate flux while increasing the energy required to operate the system. Comprehensive design and optimization of RO systems are best served by an understanding of the coupling between membrane shape, local flow field, and fouling; however, current studies focus exclusively on simplified steady-state models that ignore the dynamic coupling between fluid flow, solute transport, and foulant accumulation. We developed a customized solver (SUMs: Stanford University Membrane Solver) under the open source finite volume simulator OpenFOAM to solve transient Navier–Stokes, advection–diffusion, and adsorption–desorption equations for foulant accumulation. We implemented two permeate flux reduction models at the membrane boundary: the resistance-in-series (RIS) model and the effective-pressure-drop (EPD) model. The two models were validated against filtration experiments by comparing the equilibrium flux, pressure drop, and fouling pattern on the membrane. Both models not only predict macroscopic quantities (e.g., permeate flux and pressure drop) but also the fouling pattern developed on the membrane, with a good match with experimental results. Furthermore, the models capture the temporal evolution of foulant accumulation and its coupling with flux reduction.https://www.mdpi.com/2077-0375/11/5/349RO membranenumerical modelOpenFoam
spellingShingle Bowen Ling
Peng Xie
David Ladner
Ilenia Battiato
Dynamic Modeling of Fouling in Reverse Osmosis Membranes
Membranes
RO membrane
numerical model
OpenFoam
title Dynamic Modeling of Fouling in Reverse Osmosis Membranes
title_full Dynamic Modeling of Fouling in Reverse Osmosis Membranes
title_fullStr Dynamic Modeling of Fouling in Reverse Osmosis Membranes
title_full_unstemmed Dynamic Modeling of Fouling in Reverse Osmosis Membranes
title_short Dynamic Modeling of Fouling in Reverse Osmosis Membranes
title_sort dynamic modeling of fouling in reverse osmosis membranes
topic RO membrane
numerical model
OpenFoam
url https://www.mdpi.com/2077-0375/11/5/349
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