New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway
Two new reaction frameworks with high stereospecificity and high yields are described. Azidopolysilanes offers multiple options for obtaining aminopolysilanes, either by reducing the azido group using the Staudinger technique or by Huisgen 1,3 cycloaddition reaction with ethynylaniline. The obtained...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Publishing House of the Romanian Academy
2014-10-01
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| Series: | Memoirs of the Scientific Sections of the Romanian Academy |
| Subjects: | |
| Online Access: | http://mss.academiaromana-is.ro/mem_sc_st_2014/1_Dascalu.pdf |
| _version_ | 1818033100979961856 |
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| author | Andrei Dascalu Rodinel Ardeleanu Bogdan C. Simionescu |
| author_facet | Andrei Dascalu Rodinel Ardeleanu Bogdan C. Simionescu |
| author_sort | Andrei Dascalu |
| collection | DOAJ |
| description | Two new reaction frameworks with high stereospecificity and high yields are described. Azidopolysilanes offers multiple options for obtaining aminopolysilanes, either by reducing the azido group using the Staudinger technique or by Huisgen 1,3 cycloaddition reaction with ethynylaniline. The obtained aminopolysilanes were structurally characterized by 1H-NMR, FT-IR, elemental analysis. The optical properties were determined by fluorescence spectroscopy. |
| first_indexed | 2024-12-10T06:17:54Z |
| format | Article |
| id | doaj.art-fcfc5c15e1cf4869a86b5a4d271c1f2c |
| institution | Directory Open Access Journal |
| issn | 1224-1407 2343-7049 |
| language | English |
| last_indexed | 2024-12-10T06:17:54Z |
| publishDate | 2014-10-01 |
| publisher | Publishing House of the Romanian Academy |
| record_format | Article |
| series | Memoirs of the Scientific Sections of the Romanian Academy |
| spelling | doaj.art-fcfc5c15e1cf4869a86b5a4d271c1f2c2022-12-22T01:59:24ZengPublishing House of the Romanian AcademyMemoirs of the Scientific Sections of the Romanian Academy1224-14072343-70492014-10-01XXXVII71748New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathwayAndrei Dascalu0Rodinel Ardeleanu1Bogdan C. Simionescu2“Petru Poni’” Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Iasi, Romania“Petru Poni’” Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Iasi, Romania“Petru Poni’” Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Iasi, Romania; “Gheorghe Asachi” Technical University of Iasi, Department of Natural and Synthetic Polymers, Iasi, RomaniaTwo new reaction frameworks with high stereospecificity and high yields are described. Azidopolysilanes offers multiple options for obtaining aminopolysilanes, either by reducing the azido group using the Staudinger technique or by Huisgen 1,3 cycloaddition reaction with ethynylaniline. The obtained aminopolysilanes were structurally characterized by 1H-NMR, FT-IR, elemental analysis. The optical properties were determined by fluorescence spectroscopy.http://mss.academiaromana-is.ro/mem_sc_st_2014/1_Dascalu.pdffunctional polysilanesazidesHuisgen 1; 3-cycloadditionStaudinger reduction |
| spellingShingle | Andrei Dascalu Rodinel Ardeleanu Bogdan C. Simionescu New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway Memoirs of the Scientific Sections of the Romanian Academy functional polysilanes azides Huisgen 1; 3-cycloaddition Staudinger reduction |
| title | New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| title_full | New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| title_fullStr | New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| title_full_unstemmed | New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| title_short | New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| title_sort | new possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway |
| topic | functional polysilanes azides Huisgen 1; 3-cycloaddition Staudinger reduction |
| url | http://mss.academiaromana-is.ro/mem_sc_st_2014/1_Dascalu.pdf |
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