1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate
The title compound, C7H15N3P+·BF4− or [PTA-Me][BF4], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me]+ and a disordered tetrafluoroborate anion; two F a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808003401 |
| _version_ | 1798030902769483776 |
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| author | Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Alexander M. Kirillov Piotr Smoleński |
| author_facet | Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Alexander M. Kirillov Piotr Smoleński |
| author_sort | Armando J. L. Pombeiro |
| collection | DOAJ |
| description | The title compound, C7H15N3P+·BF4− or [PTA-Me][BF4], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me]+ and a disordered tetrafluoroborate anion; two F atoms are disordered equally over two sites. A network of weak intermolecular C—H...F hydrogen bonds results in a three-dimensional supramolecular assembly. |
| first_indexed | 2024-04-11T19:48:44Z |
| format | Article |
| id | doaj.art-fd2c12d334c14fe8b968bb46386f4f34 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:48:44Z |
| publishDate | 2008-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fd2c12d334c14fe8b968bb46386f4f342022-12-22T04:06:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643o556o55610.1107/S16005368080034011-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborateArmando J. L. PombeiroM. Fátima C. Guedes da SilvaAlexander M. KirillovPiotr SmoleńskiThe title compound, C7H15N3P+·BF4− or [PTA-Me][BF4], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me]+ and a disordered tetrafluoroborate anion; two F atoms are disordered equally over two sites. A network of weak intermolecular C—H...F hydrogen bonds results in a three-dimensional supramolecular assembly.http://scripts.iucr.org/cgi-bin/paper?S1600536808003401 |
| spellingShingle | Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Alexander M. Kirillov Piotr Smoleński 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate Acta Crystallographica Section E |
| title | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate |
| title_full | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate |
| title_fullStr | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate |
| title_full_unstemmed | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate |
| title_short | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate |
| title_sort | 1 methyl 1 azonia 3 5 diaza 7 phosphatricyclo 3 3 1 13 7 decane tetrafluoroborate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808003401 |
| work_keys_str_mv | AT armandojlpombeiro 1methyl1azonia35diaza7phosphatricyclo331137decanetetrafluoroborate AT mf225timacguedesdasilva 1methyl1azonia35diaza7phosphatricyclo331137decanetetrafluoroborate AT alexandermkirillov 1methyl1azonia35diaza7phosphatricyclo331137decanetetrafluoroborate AT piotrsmole324ski 1methyl1azonia35diaza7phosphatricyclo331137decanetetrafluoroborate |