Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water

Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its d...

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Main Authors: Aurélie Zamo, Catherine Rond, Ahmad Hamdan
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Plasma
Subjects:
Online Access:https://www.mdpi.com/2571-6182/7/1/4
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author Aurélie Zamo
Catherine Rond
Ahmad Hamdan
author_facet Aurélie Zamo
Catherine Rond
Ahmad Hamdan
author_sort Aurélie Zamo
collection DOAJ
description Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed.
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spelling doaj.art-fd2ebbad087743b7a2858eef1a180e112024-03-27T14:01:03ZengMDPI AGPlasma2571-61822024-01-0171496310.3390/plasma7010004Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/WaterAurélie Zamo0Catherine Rond1Ahmad Hamdan2Groupe de Physique des Plasmas, Département de Physique, Université de Montréal, Montréal, QC H2V 0B3, CanadaLaboratoire des Sciences des Procédés et des Matériaux (LSPM), CNRS UPR3407, Université Sorbonne Paris Nord, 93430 Villetaneuse, FranceGroupe de Physique des Plasmas, Département de Physique, Université de Montréal, Montréal, QC H2V 0B3, CanadaWater pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed.https://www.mdpi.com/2571-6182/7/1/4nanosecond dischargeplasma in contact with waterdegradation of polystyrene
spellingShingle Aurélie Zamo
Catherine Rond
Ahmad Hamdan
Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
Plasma
nanosecond discharge
plasma in contact with water
degradation of polystyrene
title Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
title_full Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
title_fullStr Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
title_full_unstemmed Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
title_short Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
title_sort polystyrene ps degradation induced by nanosecond electric discharge in air in contact with ps water
topic nanosecond discharge
plasma in contact with water
degradation of polystyrene
url https://www.mdpi.com/2571-6182/7/1/4
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AT ahmadhamdan polystyrenepsdegradationinducedbynanosecondelectricdischargeinairincontactwithpswater