Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
The aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MT...
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MDPI AG
2022-03-01
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Series: | Catalysts |
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Online Access: | https://www.mdpi.com/2073-4344/12/4/368 |
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author | Camila Gomes Flores Helena Schneider Benoit Louis |
author_facet | Camila Gomes Flores Helena Schneider Benoit Louis |
author_sort | Camila Gomes Flores |
collection | DOAJ |
description | The aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MTH) shifted from high selectivity toward olefins (>55%) to the sole formation of dimethyl ether (DME). Lignin acted as a bio-sourced secondary template (BSST), impacting the zeolite crystals’ shape and, thus, their physicochemical properties. |
first_indexed | 2024-03-09T11:02:44Z |
format | Article |
id | doaj.art-fd344df76b684837bad539e1578eb381 |
institution | Directory Open Access Journal |
issn | 2073-4344 |
language | English |
last_indexed | 2024-03-09T11:02:44Z |
publishDate | 2022-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Catalysts |
spelling | doaj.art-fd344df76b684837bad539e1578eb3812023-12-01T01:10:10ZengMDPI AGCatalysts2073-43442022-03-0112436810.3390/catal12040368Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite SynthesisCamila Gomes Flores0Helena Schneider1Benoit Louis2Institut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES) UMR 7515 du CNRS—Université de Strasbourg, 25 Rue Becquerel, CEDEX 2, 67087 Strasbourg, FranceChemical Engineering Department, Federal University of Rio Grande do Sul, 2777, Ramiro Barcelos, Porto Alegre 90035-007, BrazilInstitut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES) UMR 7515 du CNRS—Université de Strasbourg, 25 Rue Becquerel, CEDEX 2, 67087 Strasbourg, FranceThe aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MTH) shifted from high selectivity toward olefins (>55%) to the sole formation of dimethyl ether (DME). Lignin acted as a bio-sourced secondary template (BSST), impacting the zeolite crystals’ shape and, thus, their physicochemical properties.https://www.mdpi.com/2073-4344/12/4/368ZSM-5ligninBSSTMTH |
spellingShingle | Camila Gomes Flores Helena Schneider Benoit Louis Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis Catalysts ZSM-5 lignin BSST MTH |
title | Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis |
title_full | Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis |
title_fullStr | Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis |
title_full_unstemmed | Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis |
title_short | Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis |
title_sort | lignin as a bio sourced secondary template for zsm 5 zeolite synthesis |
topic | ZSM-5 lignin BSST MTH |
url | https://www.mdpi.com/2073-4344/12/4/368 |
work_keys_str_mv | AT camilagomesflores ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis AT helenaschneider ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis AT benoitlouis ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis |