Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis

The aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MT...

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Main Authors: Camila Gomes Flores, Helena Schneider, Benoit Louis
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/4/368
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author Camila Gomes Flores
Helena Schneider
Benoit Louis
author_facet Camila Gomes Flores
Helena Schneider
Benoit Louis
author_sort Camila Gomes Flores
collection DOAJ
description The aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MTH) shifted from high selectivity toward olefins (>55%) to the sole formation of dimethyl ether (DME). Lignin acted as a bio-sourced secondary template (BSST), impacting the zeolite crystals’ shape and, thus, their physicochemical properties.
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spelling doaj.art-fd344df76b684837bad539e1578eb3812023-12-01T01:10:10ZengMDPI AGCatalysts2073-43442022-03-0112436810.3390/catal12040368Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite SynthesisCamila Gomes Flores0Helena Schneider1Benoit Louis2Institut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES) UMR 7515 du CNRS—Université de Strasbourg, 25 Rue Becquerel, CEDEX 2, 67087 Strasbourg, FranceChemical Engineering Department, Federal University of Rio Grande do Sul, 2777, Ramiro Barcelos, Porto Alegre 90035-007, BrazilInstitut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES) UMR 7515 du CNRS—Université de Strasbourg, 25 Rue Becquerel, CEDEX 2, 67087 Strasbourg, FranceThe aim of this study was to investigate the effect of the addition of lignin as a sacrificial agent in ZSM-5 zeolite synthesis. Peculiar growths of ZSM-5 crystals leading to various textural properties were observed. Hence, the behavior in acid-catalyzed conversion of methanol into hydrocarbons (MTH) shifted from high selectivity toward olefins (>55%) to the sole formation of dimethyl ether (DME). Lignin acted as a bio-sourced secondary template (BSST), impacting the zeolite crystals’ shape and, thus, their physicochemical properties.https://www.mdpi.com/2073-4344/12/4/368ZSM-5ligninBSSTMTH
spellingShingle Camila Gomes Flores
Helena Schneider
Benoit Louis
Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
Catalysts
ZSM-5
lignin
BSST
MTH
title Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
title_full Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
title_fullStr Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
title_full_unstemmed Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
title_short Lignin as a Bio-Sourced Secondary Template for ZSM-5 Zeolite Synthesis
title_sort lignin as a bio sourced secondary template for zsm 5 zeolite synthesis
topic ZSM-5
lignin
BSST
MTH
url https://www.mdpi.com/2073-4344/12/4/368
work_keys_str_mv AT camilagomesflores ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis
AT helenaschneider ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis
AT benoitlouis ligninasabiosourcedsecondarytemplateforzsm5zeolitesynthesis