Formation Mechanism of Precursor Films at High Temperatures: A Review

Abstract The formation of a precursor film (PF) is always coupled with better wettability; thus, clarifying the formation mechanism is required to optimize the interfacial structures. However, recent research focuses on inert wetting systems at room temperature, which cannot guide practical material...

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Main Authors: Qiaoli Lin, Lu Liu, Wenqi Zhu
Format: Article
Language:English
Published: SpringerOpen 2022-03-01
Series:Chinese Journal of Mechanical Engineering
Subjects:
Online Access:https://doi.org/10.1186/s10033-022-00686-4
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author Qiaoli Lin
Lu Liu
Wenqi Zhu
author_facet Qiaoli Lin
Lu Liu
Wenqi Zhu
author_sort Qiaoli Lin
collection DOAJ
description Abstract The formation of a precursor film (PF) is always coupled with better wettability; thus, clarifying the formation mechanism is required to optimize the interfacial structures. However, recent research focuses on inert wetting systems at room temperature, which cannot guide practical material processing at high temperatures. In this review, PF formation mechanisms at high temperatures were reviewed. The mechanisms are surface diffusion, evaporation–condensation, subcutaneous infiltration, and rapid absorption and film overflow. In experimental metal/metal systems, the most probable mechanism is subcutaneous infiltration, related to the apparent contact angle, radius, and height of the gap between the substrate metal and the oxide film. The rapid absorption and film overflow mechanism usually occurs in metal/ceramic systems. The PF appearance for the adsorption mechanism must satisfy the paradox, that is, the relative inertial and high-affinity liquid/solid interface. Finally, another possible mechanism of PF appearance for the reactive wetting system at high temperatures was proposed, that is, the thin-surface transport mechanism. The PF formation is sensitive to external conditions. Therefore, it is necessary to develop thermodynamic and dynamic models for predicting and simulating PFs.
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spelling doaj.art-fd3bff0233184c8a907ec220883486c02022-12-21T19:58:43ZengSpringerOpenChinese Journal of Mechanical Engineering1000-93452192-82582022-03-0135111110.1186/s10033-022-00686-4Formation Mechanism of Precursor Films at High Temperatures: A ReviewQiaoli Lin0Lu Liu1Wenqi Zhu2State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal, Lanzhou University of TechnologyState Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal, Lanzhou University of TechnologyState Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal, Lanzhou University of TechnologyAbstract The formation of a precursor film (PF) is always coupled with better wettability; thus, clarifying the formation mechanism is required to optimize the interfacial structures. However, recent research focuses on inert wetting systems at room temperature, which cannot guide practical material processing at high temperatures. In this review, PF formation mechanisms at high temperatures were reviewed. The mechanisms are surface diffusion, evaporation–condensation, subcutaneous infiltration, and rapid absorption and film overflow. In experimental metal/metal systems, the most probable mechanism is subcutaneous infiltration, related to the apparent contact angle, radius, and height of the gap between the substrate metal and the oxide film. The rapid absorption and film overflow mechanism usually occurs in metal/ceramic systems. The PF appearance for the adsorption mechanism must satisfy the paradox, that is, the relative inertial and high-affinity liquid/solid interface. Finally, another possible mechanism of PF appearance for the reactive wetting system at high temperatures was proposed, that is, the thin-surface transport mechanism. The PF formation is sensitive to external conditions. Therefore, it is necessary to develop thermodynamic and dynamic models for predicting and simulating PFs.https://doi.org/10.1186/s10033-022-00686-4WettabilityWetting footHaloDiffusing band
spellingShingle Qiaoli Lin
Lu Liu
Wenqi Zhu
Formation Mechanism of Precursor Films at High Temperatures: A Review
Chinese Journal of Mechanical Engineering
Wettability
Wetting foot
Halo
Diffusing band
title Formation Mechanism of Precursor Films at High Temperatures: A Review
title_full Formation Mechanism of Precursor Films at High Temperatures: A Review
title_fullStr Formation Mechanism of Precursor Films at High Temperatures: A Review
title_full_unstemmed Formation Mechanism of Precursor Films at High Temperatures: A Review
title_short Formation Mechanism of Precursor Films at High Temperatures: A Review
title_sort formation mechanism of precursor films at high temperatures a review
topic Wettability
Wetting foot
Halo
Diffusing band
url https://doi.org/10.1186/s10033-022-00686-4
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AT wenqizhu formationmechanismofprecursorfilmsathightemperaturesareview