Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics

ABSTRACTNew lead-free (1-y)[0.995Bi0.5(Na0.80K0.20)0.5TiO3-0.005LiNbO3]-y[(Ba0.7Sr0.3)TiO3] or (1-y)[0.995BNKT-0.005LN]-y[BST] (where y = 0, 0.01, 0.02, 0.03, 0.04 and 0.05 mol fraction) ceramics were fabricated by a conventional sintering method with two calcination steps. All ceramics sintered at...

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Main Authors: Pimpilai Wannasut, Panupong Jaiban, Pharatree Jaita, Methee Promsawat, Orawan Khamman, Anucha Watcharapasorn
Format: Article
Language:English
Published: Taylor & Francis Group 2023-01-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/21870764.2022.2156668
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author Pimpilai Wannasut
Panupong Jaiban
Pharatree Jaita
Methee Promsawat
Orawan Khamman
Anucha Watcharapasorn
author_facet Pimpilai Wannasut
Panupong Jaiban
Pharatree Jaita
Methee Promsawat
Orawan Khamman
Anucha Watcharapasorn
author_sort Pimpilai Wannasut
collection DOAJ
description ABSTRACTNew lead-free (1-y)[0.995Bi0.5(Na0.80K0.20)0.5TiO3-0.005LiNbO3]-y[(Ba0.7Sr0.3)TiO3] or (1-y)[0.995BNKT-0.005LN]-y[BST] (where y = 0, 0.01, 0.02, 0.03, 0.04 and 0.05 mol fraction) ceramics were fabricated by a conventional sintering method with two calcination steps. All ceramics sintered at 1125°C for 2 hours showed an optimum relative density of ~98% and a linear shrinkage of ~18%. X-ray diffraction patterns indicated that all ceramics possessed a pure perovskite phase with coexisting rhombohedral and tetragonal structures. Electrical and energy harvesting properties of 0.995BNKT–0.005LN ceramics were improved with 0.03 mol fraction BST addition (d33 = 287 pC/N, d*33  = 440 pm/V, g33 = 13.40 × 10−3 V/mN and FoM = 3.85 pm2/N). From the observed results, the 0.97[0.995BNKT-0.005LN]-0.03[BST] ceramic is a promising candidate for lead-free piezoelelectric sensor-actuator and energy harvester.
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spelling doaj.art-fd43e729d7f049e3b3c262f8fc8d6a322023-03-16T08:10:11ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642023-01-01111889710.1080/21870764.2022.2156668Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramicsPimpilai Wannasut0Panupong Jaiban1Pharatree Jaita2Methee Promsawat3Orawan Khamman4Anucha Watcharapasorn5Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, ThailandFaculty of Science, Energy and Environment, King Mongkut’s University of Technology North Bangkok, Rayong Campus, Rayong 21120, ThailandDepartment of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, ThailandDivision of Physical Science, Faculty of Science, Prince of Songkla University, Songkhla 90112, ThailandDepartment of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, ThailandDepartment of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, ThailandABSTRACTNew lead-free (1-y)[0.995Bi0.5(Na0.80K0.20)0.5TiO3-0.005LiNbO3]-y[(Ba0.7Sr0.3)TiO3] or (1-y)[0.995BNKT-0.005LN]-y[BST] (where y = 0, 0.01, 0.02, 0.03, 0.04 and 0.05 mol fraction) ceramics were fabricated by a conventional sintering method with two calcination steps. All ceramics sintered at 1125°C for 2 hours showed an optimum relative density of ~98% and a linear shrinkage of ~18%. X-ray diffraction patterns indicated that all ceramics possessed a pure perovskite phase with coexisting rhombohedral and tetragonal structures. Electrical and energy harvesting properties of 0.995BNKT–0.005LN ceramics were improved with 0.03 mol fraction BST addition (d33 = 287 pC/N, d*33  = 440 pm/V, g33 = 13.40 × 10−3 V/mN and FoM = 3.85 pm2/N). From the observed results, the 0.97[0.995BNKT-0.005LN]-0.03[BST] ceramic is a promising candidate for lead-free piezoelelectric sensor-actuator and energy harvester.https://www.tandfonline.com/doi/10.1080/21870764.2022.2156668Bismuth sodium potassium titanatestrain behaviorpiezoelectric propertieslead-free piezoelectricenergy harvesting
spellingShingle Pimpilai Wannasut
Panupong Jaiban
Pharatree Jaita
Methee Promsawat
Orawan Khamman
Anucha Watcharapasorn
Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
Journal of Asian Ceramic Societies
Bismuth sodium potassium titanate
strain behavior
piezoelectric properties
lead-free piezoelectric
energy harvesting
title Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
title_full Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
title_fullStr Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
title_full_unstemmed Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
title_short Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics
title_sort improvement of electrical and energy harvesting properties of new lead free bst modified 0 995bnkt 0 005ln ceramics
topic Bismuth sodium potassium titanate
strain behavior
piezoelectric properties
lead-free piezoelectric
energy harvesting
url https://www.tandfonline.com/doi/10.1080/21870764.2022.2156668
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