Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates
Two triorganotin ferrocenecarboxylates, C5 H5 FeC5 H4 COOSnR3 (R=C6 H11-c, 1; C6 H5 C(CH3)2 CH2, 2), have been synthesized by the reaction of ferrocenecarboxylic acid with triorganotin hydroxide in benzene and characterized by means of elemental analysis, FT-IR, 1H NMR spectroscopy and X-ray single...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2014-07-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2014-0027 |
| _version_ | 1819130396395175936 |
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| author | Dong Yunsai Yu You Tian Laijin |
| author_facet | Dong Yunsai Yu You Tian Laijin |
| author_sort | Dong Yunsai |
| collection | DOAJ |
| description | Two triorganotin ferrocenecarboxylates, C5 H5 FeC5 H4 COOSnR3 (R=C6 H11-c, 1; C6 H5 C(CH3)2 CH2, 2), have been synthesized by the reaction of ferrocenecarboxylic acid with triorganotin hydroxide in benzene and characterized by means of elemental analysis, FT-IR, 1H NMR spectroscopy and X-ray single crystal diffraction. The carboxylate in the compounds is monodentate, and the tin atom adopts distorted tetrahedral coordination geometry. Bioassay results have shown that the compounds have good in vitro antibacterial activity. |
| first_indexed | 2024-12-22T08:58:57Z |
| format | Article |
| id | doaj.art-fd62b9cea10b4c05afc221261cb097ad |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-22T08:58:57Z |
| publishDate | 2014-07-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-fd62b9cea10b4c05afc221261cb097ad2022-12-21T18:31:46ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192014-07-01373-4919510.1515/mgmc-2014-0027Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylatesDong Yunsai0Yu You1Tian Laijin2Key Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaKey Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaKey Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaTwo triorganotin ferrocenecarboxylates, C5 H5 FeC5 H4 COOSnR3 (R=C6 H11-c, 1; C6 H5 C(CH3)2 CH2, 2), have been synthesized by the reaction of ferrocenecarboxylic acid with triorganotin hydroxide in benzene and characterized by means of elemental analysis, FT-IR, 1H NMR spectroscopy and X-ray single crystal diffraction. The carboxylate in the compounds is monodentate, and the tin atom adopts distorted tetrahedral coordination geometry. Bioassay results have shown that the compounds have good in vitro antibacterial activity.https://doi.org/10.1515/mgmc-2014-0027antibacterial activitycrystal structureferrocenecarboxylic acidorganotin |
| spellingShingle | Dong Yunsai Yu You Tian Laijin Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates Main Group Metal Chemistry antibacterial activity crystal structure ferrocenecarboxylic acid organotin |
| title | Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| title_full | Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| title_fullStr | Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| title_full_unstemmed | Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| title_short | Synthesis, structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| title_sort | synthesis structural characterization and antibacterial activity of triorganotin ferrocenecarboxylates |
| topic | antibacterial activity crystal structure ferrocenecarboxylic acid organotin |
| url | https://doi.org/10.1515/mgmc-2014-0027 |
| work_keys_str_mv | AT dongyunsai synthesisstructuralcharacterizationandantibacterialactivityoftriorganotinferrocenecarboxylates AT yuyou synthesisstructuralcharacterizationandantibacterialactivityoftriorganotinferrocenecarboxylates AT tianlaijin synthesisstructuralcharacterizationandantibacterialactivityoftriorganotinferrocenecarboxylates |