Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.

Ambient monitoring analyses may identify potential new public health hazards such as residual levels of fumigants and industrial chemicals off gassing from products and goods shipped globally. We analyzed container air with gas chromatography coupled to mass spectrometry (TD-2D-GC-MS/FPD) and assess...

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Main Authors: Lygia Therese Budnik, Nadine Austel, Sabrina Gadau, Stefan Kloth, Jens Schubert, Harald Jungnickel, Andreas Luch
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2017-01-01
Series:PLoS ONE
Online Access:http://europepmc.org/articles/PMC5435304?pdf=render
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author Lygia Therese Budnik
Nadine Austel
Sabrina Gadau
Stefan Kloth
Jens Schubert
Harald Jungnickel
Andreas Luch
author_facet Lygia Therese Budnik
Nadine Austel
Sabrina Gadau
Stefan Kloth
Jens Schubert
Harald Jungnickel
Andreas Luch
author_sort Lygia Therese Budnik
collection DOAJ
description Ambient monitoring analyses may identify potential new public health hazards such as residual levels of fumigants and industrial chemicals off gassing from products and goods shipped globally. We analyzed container air with gas chromatography coupled to mass spectrometry (TD-2D-GC-MS/FPD) and assessed whether the concentration of the volatiles benzene and 1,2-dichloroethane exceeded recommended exposure limits (REL). Products were taken from transport containers and analyzed for outgassing of volatiles. Furthermore, experimental outgassing was performed on packaging materials and textiles, to simulate the hazards tainting from globally shipped goods. The mean amounts of benzene in analyzed container air were 698-fold higher, and those of ethylene dichloride were 4.5-fold higher than the corresponding REL. More than 90% of all containers struck with toluene residues higher than its REL. For 1,2-dichloroethane 53% of containers, transporting shoes exceeded the REL. In standardized experimental fumigation of various products, outgassing of 1,2-dichloroethane under controlled laboratory conditions took up to several months. Globally produced transported products tainted with toxic industrial chemicals may contribute to the mixture of volatiles in indoor air as they are likely to emit for a long period. These results need to be taken into account for further evaluation of safety standards applying to workers and consumers.
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spelling doaj.art-fd7d7b9ea83f4d0f93259d7a80a279292022-12-21T18:24:51ZengPublic Library of Science (PLoS)PLoS ONE1932-62032017-01-01125e017736310.1371/journal.pone.0177363Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.Lygia Therese BudnikNadine AustelSabrina GadauStefan KlothJens SchubertHarald JungnickelAndreas LuchAmbient monitoring analyses may identify potential new public health hazards such as residual levels of fumigants and industrial chemicals off gassing from products and goods shipped globally. We analyzed container air with gas chromatography coupled to mass spectrometry (TD-2D-GC-MS/FPD) and assessed whether the concentration of the volatiles benzene and 1,2-dichloroethane exceeded recommended exposure limits (REL). Products were taken from transport containers and analyzed for outgassing of volatiles. Furthermore, experimental outgassing was performed on packaging materials and textiles, to simulate the hazards tainting from globally shipped goods. The mean amounts of benzene in analyzed container air were 698-fold higher, and those of ethylene dichloride were 4.5-fold higher than the corresponding REL. More than 90% of all containers struck with toluene residues higher than its REL. For 1,2-dichloroethane 53% of containers, transporting shoes exceeded the REL. In standardized experimental fumigation of various products, outgassing of 1,2-dichloroethane under controlled laboratory conditions took up to several months. Globally produced transported products tainted with toxic industrial chemicals may contribute to the mixture of volatiles in indoor air as they are likely to emit for a long period. These results need to be taken into account for further evaluation of safety standards applying to workers and consumers.http://europepmc.org/articles/PMC5435304?pdf=render
spellingShingle Lygia Therese Budnik
Nadine Austel
Sabrina Gadau
Stefan Kloth
Jens Schubert
Harald Jungnickel
Andreas Luch
Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
PLoS ONE
title Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
title_full Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
title_fullStr Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
title_full_unstemmed Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
title_short Experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products.
title_sort experimental outgassing of toxic chemicals to simulate the characteristics of hazards tainting globally shipped products
url http://europepmc.org/articles/PMC5435304?pdf=render
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