Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide

An aqueous ribose-cysteine model system, heated at 140°C under supercritical carbon dioxide (SC-CO2) and supercritical nitrogen (SC-N2), was investigated with emphasis on the formation of volatile compounds. In general, SC-CO2 facilitated the overall intermediates accumulation while suppressing the...

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Main Authors: Honggao Xu, Wenhao He, Xuan Liu, Yanxiang Gao
Format: Article
Language:English
Published: Czech Academy of Agricultural Sciences 2010-06-01
Series:Czech Journal of Food Sciences
Subjects:
Online Access:https://cjfs.agriculturejournals.cz/artkey/cjf-201003-0005_effect-of-pressure-on-the-maillard-reaction-between-ribose-and-cysteine-in-supercritical-carbon-dioxide.php
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author Honggao Xu
Wenhao He
Xuan Liu
Yanxiang Gao
author_facet Honggao Xu
Wenhao He
Xuan Liu
Yanxiang Gao
author_sort Honggao Xu
collection DOAJ
description An aqueous ribose-cysteine model system, heated at 140°C under supercritical carbon dioxide (SC-CO2) and supercritical nitrogen (SC-N2), was investigated with emphasis on the formation of volatile compounds. In general, SC-CO2 facilitated the overall intermediates accumulation while suppressing the advanced stage of browning. 3-Methyl-1, 2-dithian-4-one increased with increasing SC-CO2 pressure, and was always more concentrated than in the case of SC-N2-treatment. The formation of thiols, disulfides, and formyl substituted thiophenes was also promoted in SC-CO2-treated reaction products, while the effect of high pressure on the individual components followed different patterns. The reversible pH decrease and reinforced acid-base catalysis of 2, 3-enolisation by SC-CO2 could attribute to the decreased browning and higher amounts of most intense meaty aromatic compounds.
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spelling doaj.art-fd87b3377487413d908d148a51d83b9b2023-02-23T03:27:45ZengCzech Academy of Agricultural SciencesCzech Journal of Food Sciences1212-18001805-93172010-06-0128319220110.17221/189/2008-CJFScjf-201003-0005Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxideHonggao Xu0Wenhao He1Xuan Liu2Yanxiang Gao3College of Food Science and Nutritional Engineering, China Agricultural University, Beijing, P. R. ChinaCollege of Food Science and Nutritional Engineering, China Agricultural University, Beijing, P. R. ChinaCollege of Food Science and Nutritional Engineering, China Agricultural University, Beijing, P. R. ChinaCollege of Food Science and Nutritional Engineering, China Agricultural University, Beijing, P. R. ChinaAn aqueous ribose-cysteine model system, heated at 140°C under supercritical carbon dioxide (SC-CO2) and supercritical nitrogen (SC-N2), was investigated with emphasis on the formation of volatile compounds. In general, SC-CO2 facilitated the overall intermediates accumulation while suppressing the advanced stage of browning. 3-Methyl-1, 2-dithian-4-one increased with increasing SC-CO2 pressure, and was always more concentrated than in the case of SC-N2-treatment. The formation of thiols, disulfides, and formyl substituted thiophenes was also promoted in SC-CO2-treated reaction products, while the effect of high pressure on the individual components followed different patterns. The reversible pH decrease and reinforced acid-base catalysis of 2, 3-enolisation by SC-CO2 could attribute to the decreased browning and higher amounts of most intense meaty aromatic compounds.https://cjfs.agriculturejournals.cz/artkey/cjf-201003-0005_effect-of-pressure-on-the-maillard-reaction-between-ribose-and-cysteine-in-supercritical-carbon-dioxide.phpsupercritical carbon dioxide (sc-co2)pressuremaillard reactionribosecysteinevolatiles
spellingShingle Honggao Xu
Wenhao He
Xuan Liu
Yanxiang Gao
Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
Czech Journal of Food Sciences
supercritical carbon dioxide (sc-co2)
pressure
maillard reaction
ribose
cysteine
volatiles
title Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
title_full Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
title_fullStr Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
title_full_unstemmed Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
title_short Effect of pressure on the Maillard reaction between ribose and cysteine in supercritical carbon dioxide
title_sort effect of pressure on the maillard reaction between ribose and cysteine in supercritical carbon dioxide
topic supercritical carbon dioxide (sc-co2)
pressure
maillard reaction
ribose
cysteine
volatiles
url https://cjfs.agriculturejournals.cz/artkey/cjf-201003-0005_effect-of-pressure-on-the-maillard-reaction-between-ribose-and-cysteine-in-supercritical-carbon-dioxide.php
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