TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination

In this study, TiO2 nanoparticles were inserted into the polyamide layer of traditional thin film composite membrane. The nanoparticles were dispersed in a trimesoyl chloride-hexane solution before interfacial polymerization with m-phenylenediamine-aqueous solution. Membrane characterization was per...

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Main Author: Ahmed Al Mayyahi
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Membranes
Subjects:
Online Access:http://www.mdpi.com/2077-0375/8/3/66
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author Ahmed Al Mayyahi
author_facet Ahmed Al Mayyahi
author_sort Ahmed Al Mayyahi
collection DOAJ
description In this study, TiO2 nanoparticles were inserted into the polyamide layer of traditional thin film composite membrane. The nanoparticles were dispersed in a trimesoyl chloride-hexane solution before interfacial polymerization with m-phenylenediamine-aqueous solution. Membrane characterization was performed via contact angle measurements, atomic force microscopy (AFM), scanning electron microscopy (SEM), and water flux, salt rejection, and fouling resistance evaluation. The results indicate that TiO2 could effectively improve membrane performance. Water flux increased from 40 to 65 L/m² h by increasing NPs concentration from 0 to 0.1 wt. %, while NaCl rejection was above 96%. Moreover, the modified membrane demonstrated better organic fouling resistance and robust antibacterial efficiency.
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spelling doaj.art-fdafe62885a24f1f81aeeec8deabdcf52023-09-03T02:46:40ZengMDPI AGMembranes2077-03752018-08-01836610.3390/membranes8030066membranes8030066TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water DesalinationAhmed Al Mayyahi0Department of Chemical Engineering, University of Missouri, Columbia, MO 65211, USAIn this study, TiO2 nanoparticles were inserted into the polyamide layer of traditional thin film composite membrane. The nanoparticles were dispersed in a trimesoyl chloride-hexane solution before interfacial polymerization with m-phenylenediamine-aqueous solution. Membrane characterization was performed via contact angle measurements, atomic force microscopy (AFM), scanning electron microscopy (SEM), and water flux, salt rejection, and fouling resistance evaluation. The results indicate that TiO2 could effectively improve membrane performance. Water flux increased from 40 to 65 L/m² h by increasing NPs concentration from 0 to 0.1 wt. %, while NaCl rejection was above 96%. Moreover, the modified membrane demonstrated better organic fouling resistance and robust antibacterial efficiency.http://www.mdpi.com/2077-0375/8/3/66nanoparticles (NPs)thin film nanocomposite (TFN)reverse osmosis (RO)interfacial polymerization (IP)
spellingShingle Ahmed Al Mayyahi
TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
Membranes
nanoparticles (NPs)
thin film nanocomposite (TFN)
reverse osmosis (RO)
interfacial polymerization (IP)
title TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
title_full TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
title_fullStr TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
title_full_unstemmed TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
title_short TiO2 Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination
title_sort tio2 polyamide thin film nanocomposite reverses osmosis membrane for water desalination
topic nanoparticles (NPs)
thin film nanocomposite (TFN)
reverse osmosis (RO)
interfacial polymerization (IP)
url http://www.mdpi.com/2077-0375/8/3/66
work_keys_str_mv AT ahmedalmayyahi tio2polyamidethinfilmnanocompositereversesosmosismembraneforwaterdesalination