Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-methoxyphenyl)acetamide

Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-methoxyphenyl)acetamide

In the title molecule, C9H10ClNO2, the methoxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H...O, C—H...O and C—H...Cl hydrogen bonds plus C—H...π(ring) int...

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Bibliographic Details
Main Authors: Mohcine Missioui, Walid Guerrab, Intissar Nchioua, Abderrazzak El Moutaouakil Ala Allah, Camille Kalonji Mubengayi, Abdulsalam Alsubari, Joel T. Mague, Youssef Ramli
Format: Article
Language:English
Published: International Union of Crystallography 2022-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hydrogen bond
c—h...π(ring) interaction
acetamide
hirshfeld surface
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902200576X
Description
Summary:In the title molecule, C9H10ClNO2, the methoxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H...O, C—H...O and C—H...Cl hydrogen bonds plus C—H...π(ring) interactions. A Hirshfeld surface analysis of the intermolecular interactions was performed and indicated that C...H/H...C interactions make the largest contribution to the surface area (33.4%).
ISSN:2056-9890

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