A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing

The possibility of applying a combined concentration and metallurgical method for processing low-grade and refractory copper–nickel ores was considered. The resulting rougher and scavenger flotation concentrate contained 2.07% nickel and 0.881% copper at a recovery of 85.44% and 89.91%, respectively...

Full description

Bibliographic Details
Main Authors: Andrey A. Goryachev, Elena V. Chernousenko, Sergey S. Potapov, Nikita S. Tsvetov, Dmitriy V. Makarov
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/3/422
_version_ 1797414287552020480
author Andrey A. Goryachev
Elena V. Chernousenko
Sergey S. Potapov
Nikita S. Tsvetov
Dmitriy V. Makarov
author_facet Andrey A. Goryachev
Elena V. Chernousenko
Sergey S. Potapov
Nikita S. Tsvetov
Dmitriy V. Makarov
author_sort Andrey A. Goryachev
collection DOAJ
description The possibility of applying a combined concentration and metallurgical method for processing low-grade and refractory copper–nickel ores was considered. The resulting rougher and scavenger flotation concentrate contained 2.07% nickel and 0.881% copper at a recovery of 85.44% and 89.91%, respectively. The concentrate was then roasted with ammonium sulfate, followed by aqueous leaching of clinker to dissolve nickel and copper. The roasting temperature, the ratio of concentrate to (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> in the mixture, and the temperature were varied. Based on the study findings, the following process conditions were found to be optimal: roasting temperature 400 °C, rougher concentrate to ammonium sulfate ratio 1:7, and grinding size −40 μm. A roasting temperature of 400 °C is significantly lower than the temperature applied in conventional pyrometallurgical processes. The possibility of collecting off-gases allows the reagent to be regenerated and makes the process even more cost-effective. End-to-end recovery into pregnant solution was 81.42% for nickel and 82.81% for copper. The resulting solutions can be processed by known hydrometallurgical methods.
first_indexed 2024-03-09T05:30:52Z
format Article
id doaj.art-fde141e5284846e197801ddb1d0e75c1
institution Directory Open Access Journal
issn 2075-4701
language English
last_indexed 2024-03-09T05:30:52Z
publishDate 2021-03-01
publisher MDPI AG
record_format Article
series Metals
spelling doaj.art-fde141e5284846e197801ddb1d0e75c12023-12-03T12:33:32ZengMDPI AGMetals2075-47012021-03-0111342210.3390/met11030422A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore ProcessingAndrey A. Goryachev0Elena V. Chernousenko1Sergey S. Potapov2Nikita S. Tsvetov3Dmitriy V. Makarov4Kola Science Centre of the Russian Academy of Sciences, Institute of North Industrial Ecology Problems, Fersman St., 14a, 184209 Apatity, RussiaKola Science Centre of the Russian Academy of Sciences, Mining Institute, Fersman St., 26, 184209 Apatity, RussiaSouth Urals Federal Research Centre of Mineralogy and Geoecology UB RAS, 456317 Miass, RussiaKola Science Centre of the Russian Academy of Sciences, I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Fersman St., 26a, 184209 Apatity, RussiaKola Science Centre of the Russian Academy of Sciences, Institute of North Industrial Ecology Problems, Fersman St., 14a, 184209 Apatity, RussiaThe possibility of applying a combined concentration and metallurgical method for processing low-grade and refractory copper–nickel ores was considered. The resulting rougher and scavenger flotation concentrate contained 2.07% nickel and 0.881% copper at a recovery of 85.44% and 89.91%, respectively. The concentrate was then roasted with ammonium sulfate, followed by aqueous leaching of clinker to dissolve nickel and copper. The roasting temperature, the ratio of concentrate to (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> in the mixture, and the temperature were varied. Based on the study findings, the following process conditions were found to be optimal: roasting temperature 400 °C, rougher concentrate to ammonium sulfate ratio 1:7, and grinding size −40 μm. A roasting temperature of 400 °C is significantly lower than the temperature applied in conventional pyrometallurgical processes. The possibility of collecting off-gases allows the reagent to be regenerated and makes the process even more cost-effective. End-to-end recovery into pregnant solution was 81.42% for nickel and 82.81% for copper. The resulting solutions can be processed by known hydrometallurgical methods.https://www.mdpi.com/2075-4701/11/3/422copper–nickel oreflotationrougher concentrateammonium sulfateroastingaqueous leaching
spellingShingle Andrey A. Goryachev
Elena V. Chernousenko
Sergey S. Potapov
Nikita S. Tsvetov
Dmitriy V. Makarov
A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
Metals
copper–nickel ore
flotation
rougher concentrate
ammonium sulfate
roasting
aqueous leaching
title A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
title_full A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
title_fullStr A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
title_full_unstemmed A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
title_short A Study of the Feasibility of Using Ammonium Sulfate in Copper—Nickel Ore Processing
title_sort study of the feasibility of using ammonium sulfate in copper nickel ore processing
topic copper–nickel ore
flotation
rougher concentrate
ammonium sulfate
roasting
aqueous leaching
url https://www.mdpi.com/2075-4701/11/3/422
work_keys_str_mv AT andreyagoryachev astudyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT elenavchernousenko astudyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT sergeyspotapov astudyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT nikitastsvetov astudyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT dmitriyvmakarov astudyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT andreyagoryachev studyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT elenavchernousenko studyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT sergeyspotapov studyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT nikitastsvetov studyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing
AT dmitriyvmakarov studyofthefeasibilityofusingammoniumsulfateincoppernickeloreprocessing