Reevaluating ortho-Carborane Synthesis: Success with Mono-Substituted Acetylenes in the Presence of Silver Salts

Reevaluating ortho-Carborane Synthesis: Success with Mono-Substituted Acetylenes in the Presence of Silver Salts

The study shows that traditional methods for synthesizing ortho-carboranes from nido-B10H14 and its complexes (B10H12L2) using donor- and acceptor-disubstituted acetylenes yielding low efficiencies (yields 0 - 12%). Attempts to improve yields with ionic liquids and silver salts as catalysts were uns...

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Bibliographic Details
Main Authors: Oleh V. Svaliavyn, Artem M. Mishchenko, Yulian L. Lishchenko, Andrey P. Mityuk, Alona S. Cherednichenko, Nataliya A. Shtil, Volodymyr V. Turcheniuk, Radomyr V. Smaliy, Yuliya V. Rassukana, Olexandr Ye. Pashenko
Format: Article
Language:English
Published: National University of Pharmacy (Kharkiv) 2024-12-01
Series:Журнал органічної та фармацевтичної хімії
Subjects:
ortho-carborane
decaborane
acetylenes
silver
synthesis
Online Access:https://ophcj.nuph.edu.ua/article/view/316200

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