Ni-Based Complexes in Selective Ethylene Oligomerization Processes
Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-05-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/5/498 |
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| author | Giyjaz E. Bekmukhamedov Aleksandr V. Sukhov Aidar M. Kuchkaev Dmitry G. Yakhvarov |
| author_facet | Giyjaz E. Bekmukhamedov Aleksandr V. Sukhov Aidar M. Kuchkaev Dmitry G. Yakhvarov |
| author_sort | Giyjaz E. Bekmukhamedov |
| collection | DOAJ |
| description | Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered. |
| first_indexed | 2024-03-10T20:06:05Z |
| format | Article |
| id | doaj.art-fe1a7a8a96644c2695d90611379fa9e9 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T20:06:05Z |
| publishDate | 2020-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-fe1a7a8a96644c2695d90611379fa9e92023-11-19T23:17:45ZengMDPI AGCatalysts2073-43442020-05-0110549810.3390/catal10050498Ni-Based Complexes in Selective Ethylene Oligomerization ProcessesGiyjaz E. Bekmukhamedov0Aleksandr V. Sukhov1Aidar M. Kuchkaev2Dmitry G. Yakhvarov3Alexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya st., 420008 Kazan, RussiaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya st., 420008 Kazan, RussiaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya st., 420008 Kazan, RussiaAlexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya st., 420008 Kazan, RussiaLinear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.https://www.mdpi.com/2073-4344/10/5/498homogeneous catalysisethylene oligomerizationnickel complexescatalytic activityselectivityimine ligands |
| spellingShingle | Giyjaz E. Bekmukhamedov Aleksandr V. Sukhov Aidar M. Kuchkaev Dmitry G. Yakhvarov Ni-Based Complexes in Selective Ethylene Oligomerization Processes Catalysts homogeneous catalysis ethylene oligomerization nickel complexes catalytic activity selectivity imine ligands |
| title | Ni-Based Complexes in Selective Ethylene Oligomerization Processes |
| title_full | Ni-Based Complexes in Selective Ethylene Oligomerization Processes |
| title_fullStr | Ni-Based Complexes in Selective Ethylene Oligomerization Processes |
| title_full_unstemmed | Ni-Based Complexes in Selective Ethylene Oligomerization Processes |
| title_short | Ni-Based Complexes in Selective Ethylene Oligomerization Processes |
| title_sort | ni based complexes in selective ethylene oligomerization processes |
| topic | homogeneous catalysis ethylene oligomerization nickel complexes catalytic activity selectivity imine ligands |
| url | https://www.mdpi.com/2073-4344/10/5/498 |
| work_keys_str_mv | AT giyjazebekmukhamedov nibasedcomplexesinselectiveethyleneoligomerizationprocesses AT aleksandrvsukhov nibasedcomplexesinselectiveethyleneoligomerizationprocesses AT aidarmkuchkaev nibasedcomplexesinselectiveethyleneoligomerizationprocesses AT dmitrygyakhvarov nibasedcomplexesinselectiveethyleneoligomerizationprocesses |