Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies
With the aim to find new efficient extractants for recovery of f-block elements from processing wastes of different origin, we have compared a series of phosphoryl-containing podands, including (2-(diphenylphosphorylmethoxy)phenyl)diphenylphosphine oxide <b>1</b> and its analogues <b&...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-04-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/26/8/2217 |
| _version_ | 1797538031635267584 |
|---|---|
| author | Alfiya Safiulina Nataliya Borisova Mikhail Grigoriev Dmitriy Baulin Vladimir Baulin Aslan Tsivadze |
| author_facet | Alfiya Safiulina Nataliya Borisova Mikhail Grigoriev Dmitriy Baulin Vladimir Baulin Aslan Tsivadze |
| author_sort | Alfiya Safiulina |
| collection | DOAJ |
| description | With the aim to find new efficient extractants for recovery of f-block elements from processing wastes of different origin, we have compared a series of phosphoryl-containing podands, including (2-(diphenylphosphorylmethoxy)phenyl)diphenylphosphine oxide <b>1</b> and its analogues <b>5</b>–<b>7</b>, where the ArP(O)Ph<sub>2</sub> group of phosphine oxide type is replaced by phosphonic fragments. Quantum-chemical modelling of the structures of phosphoryl-containing podands <b>1</b> and <b>5</b>–<b>7</b> has been performed, which was later confirmed by the data of X-ray diffraction. The features of extraction of nitric acid, as well as U(VI), Th(IV), Nd(III), and Ho(III) with compounds <b>1</b> and <b>5</b>–<b>7</b> from nitric acid media into 1,2-dichloroethane have been studied. The compositions of extracted complexes have been determined. |
| first_indexed | 2024-03-10T12:24:41Z |
| format | Article |
| id | doaj.art-fe6289501ace4680bf283e0307077cdf |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T12:24:41Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-fe6289501ace4680bf283e0307077cdf2023-11-21T15:12:33ZengMDPI AGMolecules1420-30492021-04-01268221710.3390/molecules26082217Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction StudiesAlfiya Safiulina0Nataliya Borisova1Mikhail Grigoriev2Dmitriy Baulin3Vladimir Baulin4Aslan Tsivadze5Joint Stock Company A. A. Bochvar High-Technology Research Institute of Inorganic Materials, ul. Rogova 5a, 123098 Moscow, RussiaChemical Faculty, Moscow State University, Leninskie Gory 1, 119991 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prospect 31, Building 4, 119071 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prospect 31, Building 4, 119071 Moscow, RussiaInstitute of Physiologically Active Substances, Russian Academy of Sciences, Severnyi Proezd 1, Chernogolovka, 142432 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prospect 31, Building 4, 119071 Moscow, RussiaWith the aim to find new efficient extractants for recovery of f-block elements from processing wastes of different origin, we have compared a series of phosphoryl-containing podands, including (2-(diphenylphosphorylmethoxy)phenyl)diphenylphosphine oxide <b>1</b> and its analogues <b>5</b>–<b>7</b>, where the ArP(O)Ph<sub>2</sub> group of phosphine oxide type is replaced by phosphonic fragments. Quantum-chemical modelling of the structures of phosphoryl-containing podands <b>1</b> and <b>5</b>–<b>7</b> has been performed, which was later confirmed by the data of X-ray diffraction. The features of extraction of nitric acid, as well as U(VI), Th(IV), Nd(III), and Ho(III) with compounds <b>1</b> and <b>5</b>–<b>7</b> from nitric acid media into 1,2-dichloroethane have been studied. The compositions of extracted complexes have been determined.https://www.mdpi.com/1420-3049/26/8/2217phosphoryl-containing podandssynthesisstructurequantum-chemical modellingX-ray diffraction analysis extractionpreconcentration |
| spellingShingle | Alfiya Safiulina Nataliya Borisova Mikhail Grigoriev Dmitriy Baulin Vladimir Baulin Aslan Tsivadze Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies Molecules phosphoryl-containing podands synthesis structure quantum-chemical modelling X-ray diffraction analysis extraction preconcentration |
| title | Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies |
| title_full | Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies |
| title_fullStr | Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies |
| title_full_unstemmed | Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies |
| title_short | Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies |
| title_sort | design of extractants for f block elements in a series of 2 diphenylphosphoryl methoxyphenyl diphenylphosphine oxide derivatives synthesis quantum chemical and extraction studies |
| topic | phosphoryl-containing podands synthesis structure quantum-chemical modelling X-ray diffraction analysis extraction preconcentration |
| url | https://www.mdpi.com/1420-3049/26/8/2217 |
| work_keys_str_mv | AT alfiyasafiulina designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies AT nataliyaborisova designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies AT mikhailgrigoriev designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies AT dmitriybaulin designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies AT vladimirbaulin designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies AT aslantsivadze designofextractantsforfblockelementsinaseriesof2diphenylphosphorylmethoxyphenyldiphenylphosphineoxidederivativessynthesisquantumchemicalandextractionstudies |