cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate
In the title complex, [CoCl2(C12H8N2)2]·C3H7NO, which has twofold rotation symmetry, the CoII cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex molecules...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808030341 |
| _version_ | 1819125359151415296 |
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| author | Yun Chen Hui Li Shao-Ming Ying Shuang-Lian Cai |
| author_facet | Yun Chen Hui Li Shao-Ming Ying Shuang-Lian Cai |
| author_sort | Yun Chen |
| collection | DOAJ |
| description | In the title complex, [CoCl2(C12H8N2)2]·C3H7NO, which has twofold rotation symmetry, the CoII cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex molecules connected by C—H...π interactions and non-classical C—H...Cl hydrogen bonds. The cavities are occupied by the disordered dimethylformamide solvent molecule. The C and N atoms of the C—N bond in the solvent molecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis. |
| first_indexed | 2024-12-22T07:38:53Z |
| format | Article |
| id | doaj.art-fe7c556d08fe4f828d0ab535092bc070 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T07:38:53Z |
| publishDate | 2008-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fe7c556d08fe4f828d0ab535092bc0702022-12-21T18:33:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1328m132910.1107/S1600536808030341cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvateYun ChenHui LiShao-Ming YingShuang-Lian CaiIn the title complex, [CoCl2(C12H8N2)2]·C3H7NO, which has twofold rotation symmetry, the CoII cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex molecules connected by C—H...π interactions and non-classical C—H...Cl hydrogen bonds. The cavities are occupied by the disordered dimethylformamide solvent molecule. The C and N atoms of the C—N bond in the solvent molecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808030341 |
| spellingShingle | Yun Chen Hui Li Shao-Ming Ying Shuang-Lian Cai cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate Acta Crystallographica Section E |
| title | cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
| title_full | cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
| title_fullStr | cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
| title_full_unstemmed | cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
| title_short | cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
| title_sort | cis dichloridobis 1 10 phenanthroline cobalt ii dimethylformamide solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808030341 |
| work_keys_str_mv | AT yunchen cisdichloridobis110phenanthrolinecobaltiidimethylformamidesolvate AT huili cisdichloridobis110phenanthrolinecobaltiidimethylformamidesolvate AT shaomingying cisdichloridobis110phenanthrolinecobaltiidimethylformamidesolvate AT shuangliancai cisdichloridobis110phenanthrolinecobaltiidimethylformamidesolvate |