Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles.
The polar surface and hydrophilicity of starch nanoparticles (SNPs) result in their poor dispersibility in nonpolar solvent and poor compatibility with hydrophobic polymers, which limited the application in hydrophobic system. To improve their hydrophobicity, SNPs prepared through self-assembly of s...
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Public Library of Science (PLoS)
2016-01-01
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Series: | PLoS ONE |
Online Access: | http://europepmc.org/articles/PMC4769086?pdf=render |
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author | Suisui Jiang Lei Dai Yang Qin Liu Xiong Qingjie Sun |
author_facet | Suisui Jiang Lei Dai Yang Qin Liu Xiong Qingjie Sun |
author_sort | Suisui Jiang |
collection | DOAJ |
description | The polar surface and hydrophilicity of starch nanoparticles (SNPs) result in their poor dispersibility in nonpolar solvent and poor compatibility with hydrophobic polymers, which limited the application in hydrophobic system. To improve their hydrophobicity, SNPs prepared through self-assembly of short chain amylose debranched from cooked taro starch, were modified by octenyl succinic anhydride (OSA). Size via dynamic light scattering of OSA-SNPs increased compared with SNPs. Fourier transform infrared spectroscopy data indicated the OSA-SNPs had a new absorption peak at 1727 cm-1, which was the characteristic peak of carbonyl, indicating the formation of the ester bond. The dispersibility of the modified SNPs in the mixture of water with nonpolar solvent increased with increasing of degree of substitution (DS). OSA-SNPs appear to be a potential agent to stabilize the oil-water systems. |
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institution | Directory Open Access Journal |
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language | English |
last_indexed | 2024-12-10T14:15:01Z |
publishDate | 2016-01-01 |
publisher | Public Library of Science (PLoS) |
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spelling | doaj.art-fe8968a889e4444a994e0183834dd59b2022-12-22T01:45:22ZengPublic Library of Science (PLoS)PLoS ONE1932-62032016-01-01112e015004310.1371/journal.pone.0150043Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles.Suisui JiangLei DaiYang QinLiu XiongQingjie SunThe polar surface and hydrophilicity of starch nanoparticles (SNPs) result in their poor dispersibility in nonpolar solvent and poor compatibility with hydrophobic polymers, which limited the application in hydrophobic system. To improve their hydrophobicity, SNPs prepared through self-assembly of short chain amylose debranched from cooked taro starch, were modified by octenyl succinic anhydride (OSA). Size via dynamic light scattering of OSA-SNPs increased compared with SNPs. Fourier transform infrared spectroscopy data indicated the OSA-SNPs had a new absorption peak at 1727 cm-1, which was the characteristic peak of carbonyl, indicating the formation of the ester bond. The dispersibility of the modified SNPs in the mixture of water with nonpolar solvent increased with increasing of degree of substitution (DS). OSA-SNPs appear to be a potential agent to stabilize the oil-water systems.http://europepmc.org/articles/PMC4769086?pdf=render |
spellingShingle | Suisui Jiang Lei Dai Yang Qin Liu Xiong Qingjie Sun Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. PLoS ONE |
title | Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. |
title_full | Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. |
title_fullStr | Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. |
title_full_unstemmed | Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. |
title_short | Preparation and Characterization of Octenyl Succinic Anhydride Modified Taro Starch Nanoparticles. |
title_sort | preparation and characterization of octenyl succinic anhydride modified taro starch nanoparticles |
url | http://europepmc.org/articles/PMC4769086?pdf=render |
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