Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor

Silver tungstate (Ag2WO4) based materials are intensively studied because of their unique chemical and physical properties. Ag2WO4 polymorphs present discrete and intrinsically complex architectures due to a multifaceted framework derived from the different local coordination of Ag and W cations. Th...

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Main Authors: A.F. Gouveia, R.A. Roca, N.G. Macedo, L.S. Cavalcante, E. Longo, M.A. San-Miguel, A. Altomare, G.S. da Silva, J. Andrés
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422017124
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author A.F. Gouveia
R.A. Roca
N.G. Macedo
L.S. Cavalcante
E. Longo
M.A. San-Miguel
A. Altomare
G.S. da Silva
J. Andrés
author_facet A.F. Gouveia
R.A. Roca
N.G. Macedo
L.S. Cavalcante
E. Longo
M.A. San-Miguel
A. Altomare
G.S. da Silva
J. Andrés
author_sort A.F. Gouveia
collection DOAJ
description Silver tungstate (Ag2WO4) based materials are intensively studied because of their unique chemical and physical properties. Ag2WO4 polymorphs present discrete and intrinsically complex architectures due to a multifaceted framework derived from the different local coordination of Ag and W cations. This review starts with an overview of the synthesis of the three existing polymorphs (α, β, and γ) and their structures. Then, the synthesis methods, surface modification, doping process, formation of solid solutions and heterojunctions, involving Ag2WO4, and the effect of electron beam/femtosecond laser irradiation have been exemplified and discussed in detail. Finally, existing challenges and future development are also provided to shed light on the application of highly efficient Ag2WO4-based materials.
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spelling doaj.art-fea72895b4084872a442eee04f16113a2022-12-22T03:01:25ZengElsevierJournal of Materials Research and Technology2238-78542022-11-012140234051Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductorA.F. Gouveia0R.A. Roca1N.G. Macedo2L.S. Cavalcante3E. Longo4M.A. San-Miguel5A. Altomare6G.S. da Silva7J. Andrés8Department of Analytical and Physical Chemistry, University Jaume I (UJI), Castelló, 12071, Spain; Institute of Chemistry, State University of Campinas, 13083-970, Campinas, São Paulo, Brazil; Corresponding author. Department of Analytical and Physical Chemistry, University Jaume I (UJI), Castelló 12071, Spain.CDMF, Universidade Federal de São Carlos, 14800-060, São Carlos, SP, Brazil; Department of Chemistry, Instituto Federal de Educação, Ciência e Tecnologia de Maranha - IFMA, Campus: Monte Castelo, São Luiz, MA, BrazilInstitute of Chemistry, State University of Campinas, 13083-970, Campinas, São Paulo, BrazilPPGQ-GERATEC-CETEM, Universidade Estadual Do Piauí, Rua: João Cabral, N. 2231, P.O. Box 381, 64002-150, Teresina, PI, BrazilCDMF, Universidade Federal de São Carlos, 14800-060, São Carlos, SP, BrazilInstitute of Chemistry, State University of Campinas, 13083-970, Campinas, São Paulo, BrazilInstitute of Crystallography-CNR, Via G. Amendola 122/o, 70126, Bari, ItalyDepartment of Chemistry, Instituto Federal de Educação, Ciência e Tecnologia de Maranha - IFMA, Campus: Monte Castelo, São Luiz, MA, BrazilDepartment of Analytical and Physical Chemistry, University Jaume I (UJI), Castelló, 12071, Spain; Corresponding author.Silver tungstate (Ag2WO4) based materials are intensively studied because of their unique chemical and physical properties. Ag2WO4 polymorphs present discrete and intrinsically complex architectures due to a multifaceted framework derived from the different local coordination of Ag and W cations. This review starts with an overview of the synthesis of the three existing polymorphs (α, β, and γ) and their structures. Then, the synthesis methods, surface modification, doping process, formation of solid solutions and heterojunctions, involving Ag2WO4, and the effect of electron beam/femtosecond laser irradiation have been exemplified and discussed in detail. Finally, existing challenges and future development are also provided to shed light on the application of highly efficient Ag2WO4-based materials.http://www.sciencedirect.com/science/article/pii/S2238785422017124α-, β-, γ-Ag2WO4 crystalsSemiconductorMultifunctional materialMorphologyTechnological applications
spellingShingle A.F. Gouveia
R.A. Roca
N.G. Macedo
L.S. Cavalcante
E. Longo
M.A. San-Miguel
A. Altomare
G.S. da Silva
J. Andrés
Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
Journal of Materials Research and Technology
α-, β-, γ-Ag2WO4 crystals
Semiconductor
Multifunctional material
Morphology
Technological applications
title Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
title_full Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
title_fullStr Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
title_full_unstemmed Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
title_short Ag2WO4 as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor
title_sort ag2wo4 as a multifunctional material fundamentals and progress of an extraordinarily versatile semiconductor
topic α-, β-, γ-Ag2WO4 crystals
Semiconductor
Multifunctional material
Morphology
Technological applications
url http://www.sciencedirect.com/science/article/pii/S2238785422017124
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