trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) a...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812048465 |
| _version_ | 1819350238359453696 |
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| author | Wade L. Davis Reinout Meijboom |
| author_facet | Wade L. Davis Reinout Meijboom |
| author_sort | Wade L. Davis |
| collection | DOAJ |
| description | In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. |
| first_indexed | 2024-12-24T19:13:14Z |
| format | Article |
| id | doaj.art-fec4d6987f4946d4a1027b3d01d12bd8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T19:13:14Z |
| publishDate | 2012-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fec4d6987f4946d4a1027b3d01d12bd82022-12-21T16:42:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1561m156110.1107/S1600536812048465trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvateWade L. DavisReinout MeijboomIn the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155].http://scripts.iucr.org/cgi-bin/paper?S1600536812048465 |
| spellingShingle | Wade L. Davis Reinout Meijboom trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate Acta Crystallographica Section E |
| title | trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate |
| title_full | trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate |
| title_fullStr | trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate |
| title_full_unstemmed | trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate |
| title_short | trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate |
| title_sort | trans dichloridobis dicyclohexyl 4 dimethylamino phenyl phosphane amp 954 p platinum ii dichloromethane disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812048465 |
| work_keys_str_mv | AT wadeldavis transdichloridobisdicyclohexyl4dimethylaminophenylphosphaneamp954pplatinumiidichloromethanedisolvate AT reinoutmeijboom transdichloridobisdicyclohexyl4dimethylaminophenylphosphaneamp954pplatinumiidichloromethanedisolvate |