Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution

This research was focused on the discovery of new environmentally friendly sensors based on nanoscale materials whose main purpose was to detect the presence of heavy metals in aqueous solutions. The environmentally friendly extracellular biosynthetic technique was applied to produce silver nanopart...

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Main Authors: Henry Fonda Aritonang, Talita Kojong, Harry Koleangan, Audy Denny Wuntu
Format: Article
Language:English
Published: Department of Chemistry, Universitas Gadjah Mada 2021-08-01
Series:Indonesian Journal of Chemistry
Subjects:
Online Access:https://jurnal.ugm.ac.id/ijc/article/view/64902
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author Henry Fonda Aritonang
Talita Kojong
Harry Koleangan
Audy Denny Wuntu
author_facet Henry Fonda Aritonang
Talita Kojong
Harry Koleangan
Audy Denny Wuntu
author_sort Henry Fonda Aritonang
collection DOAJ
description This research was focused on the discovery of new environmentally friendly sensors based on nanoscale materials whose main purpose was to detect the presence of heavy metals in aqueous solutions. The environmentally friendly extracellular biosynthetic technique was applied to produce silver nanoparticles (AgNps). The reducing agents used were distilled water and ethanol extract obtained from fresh leaves of Lantana camara. The silver-containing extracts (Ag-extract) were then used to detect the presence of Hg2+, Cu2+, Pb2+, and Mn2+ in aqueous solutions by the colorimetric method using UV-visible spectroscopy. The colloidal synthesis of AgNPs was then monitored by the same method. The spectrum obtained showed peaks between 430 and 450 nm according to the Plasmon absorbance of AgNP. AgNPs' size and shape were characterized using the Transmission Electron Microscopy (TEM) technique, which showed the average size varies from 1.6 to 25 nm. The colorimetric data showed that Ag-extract, both of distilled water or ethanol solvents, was the best for detecting the presence of Hg2+ followed by Mn2+. On the other hand, Ag-extract in distilled water cannot detect Cu2+, Pb2+, and Mn2+ ions, while almost all Ag-extracts in ethanol solvents could identify the presence of these metals.
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spelling doaj.art-ff01251ad30245b7994af6d0be2bbc7a2022-12-21T20:39:16ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782021-08-01214990100210.22146/ijc.6490230366Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous SolutionHenry Fonda Aritonang0Talita Kojong1Harry Koleangan2Audy Denny Wuntu3Physical Chemistry Division, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, IndonesiaPhysical Chemistry Division, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, IndonesiaPhysical Chemistry Division, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, IndonesiaPhysical Chemistry Division, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, IndonesiaThis research was focused on the discovery of new environmentally friendly sensors based on nanoscale materials whose main purpose was to detect the presence of heavy metals in aqueous solutions. The environmentally friendly extracellular biosynthetic technique was applied to produce silver nanoparticles (AgNps). The reducing agents used were distilled water and ethanol extract obtained from fresh leaves of Lantana camara. The silver-containing extracts (Ag-extract) were then used to detect the presence of Hg2+, Cu2+, Pb2+, and Mn2+ in aqueous solutions by the colorimetric method using UV-visible spectroscopy. The colloidal synthesis of AgNPs was then monitored by the same method. The spectrum obtained showed peaks between 430 and 450 nm according to the Plasmon absorbance of AgNP. AgNPs' size and shape were characterized using the Transmission Electron Microscopy (TEM) technique, which showed the average size varies from 1.6 to 25 nm. The colorimetric data showed that Ag-extract, both of distilled water or ethanol solvents, was the best for detecting the presence of Hg2+ followed by Mn2+. On the other hand, Ag-extract in distilled water cannot detect Cu2+, Pb2+, and Mn2+ ions, while almost all Ag-extracts in ethanol solvents could identify the presence of these metals.https://jurnal.ugm.ac.id/ijc/article/view/64902green synthesissilver nanoparticleslantana camara fresh leaf extractqualitative detectionheavy metal ions
spellingShingle Henry Fonda Aritonang
Talita Kojong
Harry Koleangan
Audy Denny Wuntu
Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
Indonesian Journal of Chemistry
green synthesis
silver nanoparticles
lantana camara fresh leaf extract
qualitative detection
heavy metal ions
title Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
title_full Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
title_fullStr Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
title_full_unstemmed Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
title_short Green Synthesis of Silver Nanoparticles using <i>Lantana camara</i> Fresh Leaf Extract for Qualitative Detection of Hg<sup>2+</sup>, Cu<sup>2+</sup>, Pb<sup>2+</sup>, and Mn<sup>2+</sup> in Aqueous Solution
title_sort green synthesis of silver nanoparticles using i lantana camara i fresh leaf extract for qualitative detection of hg sup 2 sup cu sup 2 sup pb sup 2 sup and mn sup 2 sup in aqueous solution
topic green synthesis
silver nanoparticles
lantana camara fresh leaf extract
qualitative detection
heavy metal ions
url https://jurnal.ugm.ac.id/ijc/article/view/64902
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