Advances in metal phosphides for sodium‐ion batteries
Abstract Sodium‐ion batteries (SIBs) have been extensively studied as the potential alternative to lithium‐ion batteries (LIBs) due to the abundant natural reserves and low price of sodium resources. Nevertheless, Na+ ions possess a larger radius than Li+, resulting in slow diffusion dynamics in ele...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2021-09-01
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| Series: | SusMat |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/sus2.19 |
| _version_ | 1818579262445191168 |
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| author | Qifei Li Dan Yang Haoliang Chen Xiang Lv Yu Jiang Yuezhan Feng Xianhong Rui Yan Yu |
| author_facet | Qifei Li Dan Yang Haoliang Chen Xiang Lv Yu Jiang Yuezhan Feng Xianhong Rui Yan Yu |
| author_sort | Qifei Li |
| collection | DOAJ |
| description | Abstract Sodium‐ion batteries (SIBs) have been extensively studied as the potential alternative to lithium‐ion batteries (LIBs) due to the abundant natural reserves and low price of sodium resources. Nevertheless, Na+ ions possess a larger radius than Li+, resulting in slow diffusion dynamics in electrode materials, and thus seeking appropriate anode materials to meet high performance standards has become a trend in the field of SIBs. In this context, owing to the advantages of high theoretical capacity and proper redox potential, metal phosphides (MPs) are considered to be the promising materials to make up for the gap of SIBs anode materials. In this review, the recent development of MPs anode materials for SIBs is reviewed and analyzed comprehensively and deeply, including the synthesis method, advanced modification strategy, electrochemical performance, and Na storage mechanism. In addition, to promote the wide application of the emerging MPs anodes for SIBs, several research emphases in the future are pointed out to overcome challenges toward the commercial application. |
| first_indexed | 2024-12-16T06:58:54Z |
| format | Article |
| id | doaj.art-ff185b4fa3454de1880004d4a51b6d6c |
| institution | Directory Open Access Journal |
| issn | 2692-4552 |
| language | English |
| last_indexed | 2024-12-16T06:58:54Z |
| publishDate | 2021-09-01 |
| publisher | Wiley |
| record_format | Article |
| series | SusMat |
| spelling | doaj.art-ff185b4fa3454de1880004d4a51b6d6c2022-12-21T22:40:13ZengWileySusMat2692-45522021-09-011335939210.1002/sus2.19Advances in metal phosphides for sodium‐ion batteriesQifei Li0Dan Yang1Haoliang Chen2Xiang Lv3Yu Jiang4Yuezhan Feng5Xianhong Rui6Yan Yu7School of Materials and Energy Guangdong University of Technology Guangzhou ChinaSchool of Materials and Energy Guangdong University of Technology Guangzhou ChinaSchool of Materials and Energy Guangdong University of Technology Guangzhou ChinaSchool of Materials and Energy Guangdong University of Technology Guangzhou ChinaSchool of Materials and Energy Guangdong University of Technology Guangzhou ChinaKey Laboratory of Materials Processing and Mold, Ministry of Education Zhengzhou University Zhengzhou ChinaSchool of Materials and Energy Guangdong University of Technology Guangzhou ChinaHefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion University of Science and Technology of China Hefei Anhui ChinaAbstract Sodium‐ion batteries (SIBs) have been extensively studied as the potential alternative to lithium‐ion batteries (LIBs) due to the abundant natural reserves and low price of sodium resources. Nevertheless, Na+ ions possess a larger radius than Li+, resulting in slow diffusion dynamics in electrode materials, and thus seeking appropriate anode materials to meet high performance standards has become a trend in the field of SIBs. In this context, owing to the advantages of high theoretical capacity and proper redox potential, metal phosphides (MPs) are considered to be the promising materials to make up for the gap of SIBs anode materials. In this review, the recent development of MPs anode materials for SIBs is reviewed and analyzed comprehensively and deeply, including the synthesis method, advanced modification strategy, electrochemical performance, and Na storage mechanism. In addition, to promote the wide application of the emerging MPs anodes for SIBs, several research emphases in the future are pointed out to overcome challenges toward the commercial application.https://doi.org/10.1002/sus2.19anode materialshigh capacitymetal phosphidesNa storage mechanismsodium ion batteries |
| spellingShingle | Qifei Li Dan Yang Haoliang Chen Xiang Lv Yu Jiang Yuezhan Feng Xianhong Rui Yan Yu Advances in metal phosphides for sodium‐ion batteries SusMat anode materials high capacity metal phosphides Na storage mechanism sodium ion batteries |
| title | Advances in metal phosphides for sodium‐ion batteries |
| title_full | Advances in metal phosphides for sodium‐ion batteries |
| title_fullStr | Advances in metal phosphides for sodium‐ion batteries |
| title_full_unstemmed | Advances in metal phosphides for sodium‐ion batteries |
| title_short | Advances in metal phosphides for sodium‐ion batteries |
| title_sort | advances in metal phosphides for sodium ion batteries |
| topic | anode materials high capacity metal phosphides Na storage mechanism sodium ion batteries |
| url | https://doi.org/10.1002/sus2.19 |
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