Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear ce...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2018-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-05543-4 |
| _version_ | 1818841367688773632 |
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| author | Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin |
| author_facet | Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin |
| author_sort | Cornelius Krull |
| collection | DOAJ |
| description | Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear centre suggests a catalytically active core. |
| first_indexed | 2024-12-19T04:24:57Z |
| format | Article |
| id | doaj.art-ff2716a9ecec41f0b9f10b8ab821f7b8 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:24:57Z |
| publishDate | 2018-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-ff2716a9ecec41f0b9f10b8ab821f7b82022-12-21T20:36:04ZengNature PortfolioNature Communications2041-17232018-08-01911710.1038/s41467-018-05543-4Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulationCornelius Krull0Marina Castelli1Prokop Hapala2Dhaneesh Kumar3Anton Tadich4Martina Capsoni5Mark T. Edmonds6Jack Hellerstedt7Sarah A. Burke8Pavel Jelinek9Agustin Schiffrin10School of Physics & Astronomy, Monash UniversitySchool of Physics & Astronomy, Monash UniversityInstitute of Physics of the CASSchool of Physics & Astronomy, Monash UniversityAustralian SynchrotronDepartment of Physics and Astronomy, University of British ColumbiaSchool of Physics & Astronomy, Monash UniversitySchool of Physics & Astronomy, Monash UniversityDepartment of Physics and Astronomy, University of British ColumbiaInstitute of Physics of the CASSchool of Physics & Astronomy, Monash UniversityPolynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear centre suggests a catalytically active core.https://doi.org/10.1038/s41467-018-05543-4 |
| spellingShingle | Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation Nature Communications |
| title | Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation |
| title_full | Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation |
| title_fullStr | Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation |
| title_full_unstemmed | Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation |
| title_short | Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation |
| title_sort | iron based trinuclear metal organic nanostructures on a surface with local charge accumulation |
| url | https://doi.org/10.1038/s41467-018-05543-4 |
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