Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose

This article contains water vapor sorption data obtained on amorphous blends of octenyl succinic acid-modified (denoted as hydrophobically modified starch; HMS) and sucrose (S) in the anhydrous weight HMS/S ratios between 100/0 and 27/75. The water vapor sorption data was obtained gravimetrically. T...

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Main Authors: Job Ubbink, Thomas Zwick, David Hughes, Gabriela Badolato Bönisch
Format: Article
Language:English
Published: Elsevier 2018-10-01
Series:Data in Brief
Online Access:http://www.sciencedirect.com/science/article/pii/S2352340918309570
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author Job Ubbink
Thomas Zwick
David Hughes
Gabriela Badolato Bönisch
author_facet Job Ubbink
Thomas Zwick
David Hughes
Gabriela Badolato Bönisch
author_sort Job Ubbink
collection DOAJ
description This article contains water vapor sorption data obtained on amorphous blends of octenyl succinic acid-modified (denoted as hydrophobically modified starch; HMS) and sucrose (S) in the anhydrous weight HMS/S ratios between 100/0 and 27/75. The water vapor sorption data was obtained gravimetrically. The amorphous state of the blends was confirmed by X-ray diffraction. The glass transition temperatures of the phase-separated blends are listed; the blends show phase separation into a sucrose-rich phase and a HMS-rich phase, the composition of which varies with the blend ratios. The sucrose-rich phase is characterized by a glass transition temperature Tg,lower that is 40 to 90 K lower than the glass transition temperature Tg,upper of the HMS-rich phase.
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spelling doaj.art-ff2fdce24e1249dabb258d2c611aa3082022-12-22T00:15:46ZengElsevierData in Brief2352-34092018-10-012018841889Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucroseJob Ubbink0Thomas Zwick1David Hughes2Gabriela Badolato Bönisch3Food Science and Nutrition Department, California Polytechnic State University, 1 Grand Ave., San Luis Obispo, CA 93407, USA; Corresponding author.DSM Nutritional Products Ltd, Research Center Formulation & Application, P.O. Box 2676, 4002 Basel, SwitzerlandH. H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL, United KingdomDSM Nutritional Products Ltd, Research Center Formulation & Application, P.O. Box 2676, 4002 Basel, SwitzerlandThis article contains water vapor sorption data obtained on amorphous blends of octenyl succinic acid-modified (denoted as hydrophobically modified starch; HMS) and sucrose (S) in the anhydrous weight HMS/S ratios between 100/0 and 27/75. The water vapor sorption data was obtained gravimetrically. The amorphous state of the blends was confirmed by X-ray diffraction. The glass transition temperatures of the phase-separated blends are listed; the blends show phase separation into a sucrose-rich phase and a HMS-rich phase, the composition of which varies with the blend ratios. The sucrose-rich phase is characterized by a glass transition temperature Tg,lower that is 40 to 90 K lower than the glass transition temperature Tg,upper of the HMS-rich phase.http://www.sciencedirect.com/science/article/pii/S2352340918309570
spellingShingle Job Ubbink
Thomas Zwick
David Hughes
Gabriela Badolato Bönisch
Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
Data in Brief
title Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
title_full Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
title_fullStr Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
title_full_unstemmed Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
title_short Water vapor sorption and glass transition temperatures of phase-separated amorphous blends of hydrophobically-modified starch and sucrose
title_sort water vapor sorption and glass transition temperatures of phase separated amorphous blends of hydrophobically modified starch and sucrose
url http://www.sciencedirect.com/science/article/pii/S2352340918309570
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