Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications

Despite their comparable performance to commercial solar systems, lead-based perovskite (Pb-perovskite) solar cells exhibit limitations including Pb toxicity and instability for industrial applications. To address these issues, two types of Pb-free materials have been proposed as alternatives to Pb-...

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Main Authors: Yong Chan Choi, Kang-Won Jung
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/11/2284
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author Yong Chan Choi
Kang-Won Jung
author_facet Yong Chan Choi
Kang-Won Jung
author_sort Yong Chan Choi
collection DOAJ
description Despite their comparable performance to commercial solar systems, lead-based perovskite (Pb-perovskite) solar cells exhibit limitations including Pb toxicity and instability for industrial applications. To address these issues, two types of Pb-free materials have been proposed as alternatives to Pb-perovskite: perovskite-based and non-perovskite-based materials. In this review, we summarize the recent progress on solar cells based on antimony/bismuth (Sb/Bi) chalcohalides, representing Sb/Bi non-perovskite semiconductors containing chalcogenides and halides. Two types of ternary and quaternary chalcohalides are described, with their classification predicated on the fabrication method. We also highlight their utility as interfacial layers for improving other solar cells. This review provides clues for improving the performances of devices and design of multifunctional solar systems.
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spelling doaj.art-ff5efe35a0474506a111910f7adf49e82023-11-20T21:25:06ZengMDPI AGNanomaterials2079-49912020-11-011011228410.3390/nano10112284Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell ApplicationsYong Chan Choi0Kang-Won Jung1Division of Energy Technology, Daegu Gyeongbuk Institute of Science & Technology (DGIST), Daegu 42988, KoreaDivision of Energy Technology, Daegu Gyeongbuk Institute of Science & Technology (DGIST), Daegu 42988, KoreaDespite their comparable performance to commercial solar systems, lead-based perovskite (Pb-perovskite) solar cells exhibit limitations including Pb toxicity and instability for industrial applications. To address these issues, two types of Pb-free materials have been proposed as alternatives to Pb-perovskite: perovskite-based and non-perovskite-based materials. In this review, we summarize the recent progress on solar cells based on antimony/bismuth (Sb/Bi) chalcohalides, representing Sb/Bi non-perovskite semiconductors containing chalcogenides and halides. Two types of ternary and quaternary chalcohalides are described, with their classification predicated on the fabrication method. We also highlight their utility as interfacial layers for improving other solar cells. This review provides clues for improving the performances of devices and design of multifunctional solar systems.https://www.mdpi.com/2079-4991/10/11/2284antimony chalcohalidesbismuth chalcohalidessolar cells
spellingShingle Yong Chan Choi
Kang-Won Jung
Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
Nanomaterials
antimony chalcohalides
bismuth chalcohalides
solar cells
title Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
title_full Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
title_fullStr Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
title_full_unstemmed Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
title_short Recent Progress in Fabrication of Antimony/Bismuth Chalcohalides for Lead-Free Solar Cell Applications
title_sort recent progress in fabrication of antimony bismuth chalcohalides for lead free solar cell applications
topic antimony chalcohalides
bismuth chalcohalides
solar cells
url https://www.mdpi.com/2079-4991/10/11/2284
work_keys_str_mv AT yongchanchoi recentprogressinfabricationofantimonybismuthchalcohalidesforleadfreesolarcellapplications
AT kangwonjung recentprogressinfabricationofantimonybismuthchalcohalidesforleadfreesolarcellapplications