Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study
The asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
| _version_ | 1831671117530529792 |
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| author | Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev |
| author_facet | Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev |
| author_sort | Nadezhda M. Kurochkina |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis. The cations are associated into columns along the a axis through π–π interactions between the pyridine and benzene rings, with a centroid–centroid distance of 3.72 (5) Å. Intermolecular O—H...O, C—H...O and C—H...F hydrogen bonds consolidate the crystal packing. |
| first_indexed | 2024-12-19T23:29:29Z |
| format | Article |
| id | doaj.art-ff7eee9934cb427fa0b5632e3593d0d2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:29:29Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ff7eee9934cb427fa0b5632e3593d0d22022-12-21T20:01:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1349m135010.1107/S1600536809040926Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder studyNadezhda M. KurochkinaAndrey S. KuzovlevTamara P. PuryaevaYurii A. VelikodnyVladimir V. ChernyshevThe asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis. The cations are associated into columns along the a axis through π–π interactions between the pyridine and benzene rings, with a centroid–centroid distance of 3.72 (5) Å. Intermolecular O—H...O, C—H...O and C—H...F hydrogen bonds consolidate the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
| spellingShingle | Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study Acta Crystallographica Section E |
| title | Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_full | Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_fullStr | Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_full_unstemmed | Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_short | Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_sort | bis 4 amp 8242 2 3 5 6 8 9 11 12 octahydro 1 4 7 10 13 benzopentaoxacyclopentadecin 15 yl methoxy 2 2 amp 8242 6 amp 8242 2 amp 8242 amp 8242 terpyridine cadmium ii bis hexafluoridophosphate trihydrate a powder study |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
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