Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
Low-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and...
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Format: | Article |
Language: | English |
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Serbian Chemical Society
2022-01-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdf |
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author | Abdelmajid Belkhodja Benkhaled Amal Attar Tarik Bousalem Smain Choukchou Braham Esma |
author_facet | Abdelmajid Belkhodja Benkhaled Amal Attar Tarik Bousalem Smain Choukchou Braham Esma |
author_sort | Abdelmajid Belkhodja |
collection | DOAJ |
description | Low-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and adsorbent dosage, was investigated and optimized using central composite design (CCD) under response surface methodology (RSM). The analysis of variance (ANOVA) of the quadratic model and the analyzed model revealed that the models were statistically significant, with a low P-value (<0.0001) and a high correlation coefficient value (R2 = 0.93). The optimum parameters for total adsorption were as follows: adsorbent dose 0.027 g, pH 2, contact time 45 min, temperature 38°C, and Cr(VI) concentration 29.24 ppm. The findings of this study indicate that the prepared Alg@PANI beads could be effectively used to remove Cr(VI) ions from aqueous solutions. |
first_indexed | 2024-12-11T16:24:56Z |
format | Article |
id | doaj.art-ff88a159147e4ee68e409708570cc91a |
institution | Directory Open Access Journal |
issn | 0352-5139 1820-7421 |
language | English |
last_indexed | 2024-12-11T16:24:56Z |
publishDate | 2022-01-01 |
publisher | Serbian Chemical Society |
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series | Journal of the Serbian Chemical Society |
spelling | doaj.art-ff88a159147e4ee68e409708570cc91a2022-12-22T00:58:45ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212022-01-0187558960110.2298/JSC210724104A0352-51392100104AUse of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beadsAbdelmajid Belkhodja0https://orcid.org/0000-0002-7627-6914Benkhaled Amal1Attar Tarik2Bousalem Smain3Choukchou Braham Esma4Laboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, Algeria + Laboratory of Applied Chemistry, University Belhadj Bouchaib, Ain Témouchent, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, Algeria + Higher School of Applied Sciences of Tlemcen, Bel Horizon, Tlemcen, AlgeriaLaboratory of Applied Chemistry, University Belhadj Bouchaib, Ain Témouchent, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, AlgeriaLow-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and adsorbent dosage, was investigated and optimized using central composite design (CCD) under response surface methodology (RSM). The analysis of variance (ANOVA) of the quadratic model and the analyzed model revealed that the models were statistically significant, with a low P-value (<0.0001) and a high correlation coefficient value (R2 = 0.93). The optimum parameters for total adsorption were as follows: adsorbent dose 0.027 g, pH 2, contact time 45 min, temperature 38°C, and Cr(VI) concentration 29.24 ppm. The findings of this study indicate that the prepared Alg@PANI beads could be effectively used to remove Cr(VI) ions from aqueous solutions.http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdfbioadsorbentcentral composite designresponse surfaceanova |
spellingShingle | Abdelmajid Belkhodja Benkhaled Amal Attar Tarik Bousalem Smain Choukchou Braham Esma Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads Journal of the Serbian Chemical Society bioadsorbent central composite design response surface anova |
title | Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads |
title_full | Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads |
title_fullStr | Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads |
title_full_unstemmed | Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads |
title_short | Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads |
title_sort | use of experimental design to evaluate the adsorption of chromium vi by alginate polyaniline beads |
topic | bioadsorbent central composite design response surface anova |
url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdf |
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