Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads

Low-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and...

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Main Authors: Abdelmajid Belkhodja, Benkhaled Amal, Attar Tarik, Bousalem Smain, Choukchou Braham Esma
Format: Article
Language:English
Published: Serbian Chemical Society 2022-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdf
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author Abdelmajid Belkhodja
Benkhaled Amal
Attar Tarik
Bousalem Smain
Choukchou Braham Esma
author_facet Abdelmajid Belkhodja
Benkhaled Amal
Attar Tarik
Bousalem Smain
Choukchou Braham Esma
author_sort Abdelmajid Belkhodja
collection DOAJ
description Low-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and adsorbent dosage, was investigated and optimized using central composite design (CCD) under response surface methodology (RSM). The analysis of variance (ANOVA) of the quadratic model and the analyzed model revealed that the models were statistically significant, with a low P-value (<0.0001) and a high correlation coefficient value (R2 = 0.93). The optimum parameters for total adsorption were as follows: adsorbent dose 0.027 g, pH 2, contact time 45 min, temperature 38°C, and Cr(VI) concentration 29.24 ppm. The findings of this study indicate that the prepared Alg@PANI beads could be effectively used to remove Cr(VI) ions from aqueous solutions.
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spelling doaj.art-ff88a159147e4ee68e409708570cc91a2022-12-22T00:58:45ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212022-01-0187558960110.2298/JSC210724104A0352-51392100104AUse of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beadsAbdelmajid Belkhodja0https://orcid.org/0000-0002-7627-6914Benkhaled Amal1Attar Tarik2Bousalem Smain3Choukchou Braham Esma4Laboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, Algeria + Laboratory of Applied Chemistry, University Belhadj Bouchaib, Ain Témouchent, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, Algeria + Higher School of Applied Sciences of Tlemcen, Bel Horizon, Tlemcen, AlgeriaLaboratory of Applied Chemistry, University Belhadj Bouchaib, Ain Témouchent, AlgeriaLaboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Tlemcen, AlgeriaLow-cost decorated sodium alginate beads with polyaniline (Alg@PANI beads) were easily prepared using a cross-linking method, and employed for the adsorption of Cr(VI) from aqueous solutions. The effect of several influencing parameters, including temperature, contact time, Cr(VI) concentration, and adsorbent dosage, was investigated and optimized using central composite design (CCD) under response surface methodology (RSM). The analysis of variance (ANOVA) of the quadratic model and the analyzed model revealed that the models were statistically significant, with a low P-value (<0.0001) and a high correlation coefficient value (R2 = 0.93). The optimum parameters for total adsorption were as follows: adsorbent dose 0.027 g, pH 2, contact time 45 min, temperature 38°C, and Cr(VI) concentration 29.24 ppm. The findings of this study indicate that the prepared Alg@PANI beads could be effectively used to remove Cr(VI) ions from aqueous solutions.http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdfbioadsorbentcentral composite designresponse surfaceanova
spellingShingle Abdelmajid Belkhodja
Benkhaled Amal
Attar Tarik
Bousalem Smain
Choukchou Braham Esma
Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
Journal of the Serbian Chemical Society
bioadsorbent
central composite design
response surface
anova
title Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
title_full Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
title_fullStr Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
title_full_unstemmed Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
title_short Use of experimental design to evaluate the adsorption of chromium (VI) by alginate/polyaniline beads
title_sort use of experimental design to evaluate the adsorption of chromium vi by alginate polyaniline beads
topic bioadsorbent
central composite design
response surface
anova
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392100104A.pdf
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