Antioxidants in Margarine Emulsions

The lipid oxidation in margarine takes place in continuous liquid oil phase. The extension of fat interfaces in the system - emulsion of water in oil and the dispersion of fat crystals in liquid oil influences on the peroxidation, decomposition of hydroperoxides to aldehydes and the oxidative stabil...

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Main Authors: V. Filip, I. Hrádková, J. Šmidrkal
Format: Article
Language:English
Published: Czech Academy of Agricultural Sciences 2009-06-01
Series:Czech Journal of Food Sciences
Subjects:
Online Access:https://cjfs.agriculturejournals.cz/artkey/cjf-200910-0131_antioxidants-in-margarine-emulsions.php
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author V. Filip
I. Hrádková
J. Šmidrkal
author_facet V. Filip
I. Hrádková
J. Šmidrkal
author_sort V. Filip
collection DOAJ
description The lipid oxidation in margarine takes place in continuous liquid oil phase. The extension of fat interfaces in the system - emulsion of water in oil and the dispersion of fat crystals in liquid oil influences on the peroxidation, decomposition of hydroperoxides to aldehydes and the oxidative stability in the comparison with oxidation in the fat blend. Different antioxidants were used in margarine dispersions: L(+)ascorbic acid, ascorbyl palmitate and DL-α -tocopherol. Increasing polarity and decreasing molecular size of antioxidants have the positive influence on lipid oxidation: DL-α-tocopherol is the least effective antioxidant of all antioxidants, ascorbic acid is the most effective antioxidant and ascorbyl palmitate possesses similar, however, lesser effect. The combination of all three antioxidants restricts the production of hydroperoxides, the decomposition of hydroperoxides to aldehydes and the increase of oxidative stability was also achieved. Content of antioxidants 0.02% as ascorbic acid or ascorbyl palmitate mostly restrict the extent of lipid oxidation in the margarine dispersion with existent content of naturally present tocopherols in fat blend.
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spelling doaj.art-ff8d8700d4f94586878697d1d091ce4c2023-02-23T03:27:32ZengCzech Academy of Agricultural SciencesCzech Journal of Food Sciences1212-18001805-93172009-06-0127Special Issue 1S9S1110.17221/1089-CJFScjf-200910-0131Antioxidants in Margarine EmulsionsV. FilipI. Hrádková0J. Šmidrkal166 28 Prague, Czech Republic, *E-mail: vladimir.filip@vscht.cz66 28 Prague, Czech Republic, *E-mail: vladimir.filip@vscht.czThe lipid oxidation in margarine takes place in continuous liquid oil phase. The extension of fat interfaces in the system - emulsion of water in oil and the dispersion of fat crystals in liquid oil influences on the peroxidation, decomposition of hydroperoxides to aldehydes and the oxidative stability in the comparison with oxidation in the fat blend. Different antioxidants were used in margarine dispersions: L(+)ascorbic acid, ascorbyl palmitate and DL-α -tocopherol. Increasing polarity and decreasing molecular size of antioxidants have the positive influence on lipid oxidation: DL-α-tocopherol is the least effective antioxidant of all antioxidants, ascorbic acid is the most effective antioxidant and ascorbyl palmitate possesses similar, however, lesser effect. The combination of all three antioxidants restricts the production of hydroperoxides, the decomposition of hydroperoxides to aldehydes and the increase of oxidative stability was also achieved. Content of antioxidants 0.02% as ascorbic acid or ascorbyl palmitate mostly restrict the extent of lipid oxidation in the margarine dispersion with existent content of naturally present tocopherols in fat blend.https://cjfs.agriculturejournals.cz/artkey/cjf-200910-0131_antioxidants-in-margarine-emulsions.phpantioxidantascorbic acidascorbyl palmitateemulsionmargarinetocopherol
spellingShingle V. Filip
I. Hrádková
J. Šmidrkal
Antioxidants in Margarine Emulsions
Czech Journal of Food Sciences
antioxidant
ascorbic acid
ascorbyl palmitate
emulsion
margarine
tocopherol
title Antioxidants in Margarine Emulsions
title_full Antioxidants in Margarine Emulsions
title_fullStr Antioxidants in Margarine Emulsions
title_full_unstemmed Antioxidants in Margarine Emulsions
title_short Antioxidants in Margarine Emulsions
title_sort antioxidants in margarine emulsions
topic antioxidant
ascorbic acid
ascorbyl palmitate
emulsion
margarine
tocopherol
url https://cjfs.agriculturejournals.cz/artkey/cjf-200910-0131_antioxidants-in-margarine-emulsions.php
work_keys_str_mv AT vfilip antioxidantsinmargarineemulsions
AT ihradkova antioxidantsinmargarineemulsions
AT jsmidrkal antioxidantsinmargarineemulsions