Continuous Sizing and Identification of Microplastics in Water

The pollution of the environment with microplastics in general, and in particular, the contamination of our drinking water and other food items, has increasingly become the focus of public attention in recent years. In order to better understand the entry pathways into the human food chain and thus...

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Main Authors: Felix Glöckler, Florian Foschum, Alwin Kienle
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/23/2/781
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author Felix Glöckler
Florian Foschum
Alwin Kienle
author_facet Felix Glöckler
Florian Foschum
Alwin Kienle
author_sort Felix Glöckler
collection DOAJ
description The pollution of the environment with microplastics in general, and in particular, the contamination of our drinking water and other food items, has increasingly become the focus of public attention in recent years. In order to better understand the entry pathways into the human food chain and thus prevent them if possible, a precise characterization of the particles concerning their size and material is indispensable. Particularly small plastic particles pose a special challenge since their material can only be determined by means of large experimental effort. In this work, we present a proof of principle experiment that allows the precise determination of the plastic type and the particle size in a single step. The experiment combines elastic light scattering (Mie scattering) with inelastic light scattering (Raman scattering), the latter being used to determine the plastic type. We conducted Monte Carlo simluations for the elastically scattered light for different kinds of plastics in a microfluidic cuvette which we could reproduce in the experiment. We were able to measure the Raman signals for different microplastics in the same measurement as the elastically scattered light and thereby determine their material. This information was used to select the appropriate Monte Carlo simulation data and to assign the correct particle size to different materials with only one calibration measurement.
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spelling doaj.art-ff8e3c7e98544e1fac2ffad2ca3e148c2023-12-01T00:27:30ZengMDPI AGSensors1424-82202023-01-0123278110.3390/s23020781Continuous Sizing and Identification of Microplastics in WaterFelix Glöckler0Florian Foschum1Alwin Kienle2Institute for Lasertechnologies in Medicine and Metrology (ILM), Helmholtzstr. 12, 89081 Ulm, GermanyInstitute for Lasertechnologies in Medicine and Metrology (ILM), Helmholtzstr. 12, 89081 Ulm, GermanyInstitute for Lasertechnologies in Medicine and Metrology (ILM), Helmholtzstr. 12, 89081 Ulm, GermanyThe pollution of the environment with microplastics in general, and in particular, the contamination of our drinking water and other food items, has increasingly become the focus of public attention in recent years. In order to better understand the entry pathways into the human food chain and thus prevent them if possible, a precise characterization of the particles concerning their size and material is indispensable. Particularly small plastic particles pose a special challenge since their material can only be determined by means of large experimental effort. In this work, we present a proof of principle experiment that allows the precise determination of the plastic type and the particle size in a single step. The experiment combines elastic light scattering (Mie scattering) with inelastic light scattering (Raman scattering), the latter being used to determine the plastic type. We conducted Monte Carlo simluations for the elastically scattered light for different kinds of plastics in a microfluidic cuvette which we could reproduce in the experiment. We were able to measure the Raman signals for different microplastics in the same measurement as the elastically scattered light and thereby determine their material. This information was used to select the appropriate Monte Carlo simulation data and to assign the correct particle size to different materials with only one calibration measurement.https://www.mdpi.com/1424-8220/23/2/781microplasticMonte Carlo simulationsRaman spectroscopylight scattering
spellingShingle Felix Glöckler
Florian Foschum
Alwin Kienle
Continuous Sizing and Identification of Microplastics in Water
Sensors
microplastic
Monte Carlo simulations
Raman spectroscopy
light scattering
title Continuous Sizing and Identification of Microplastics in Water
title_full Continuous Sizing and Identification of Microplastics in Water
title_fullStr Continuous Sizing and Identification of Microplastics in Water
title_full_unstemmed Continuous Sizing and Identification of Microplastics in Water
title_short Continuous Sizing and Identification of Microplastics in Water
title_sort continuous sizing and identification of microplastics in water
topic microplastic
Monte Carlo simulations
Raman spectroscopy
light scattering
url https://www.mdpi.com/1424-8220/23/2/781
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