Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste
This work was carried out with the objective of studying the process of adsorption of Pb2+ ions by barley dust, Hordeum vulgare L. The adsorbent material was prepared by boiling in water with consequent sedimentation, drying, grinding and sieving. Kinetic, isothermal and thermodynamic studies were c...
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| Format: | Article |
| Language: | English |
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Elsevier
2023-12-01
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| Series: | Results in Chemistry |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715623004447 |
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| author | Alex Gonçalves Feitosa Yannice Tatiane da Costa Santos Jorge Marcell Coelho Menezes Henrique Douglas Melo Coutinho Victor Feitosa Teixeira João Hermínio da Silva Francisco José de Paula Filho Raimundo Nonato Pereira Teixeira Thiago Mielle Brito Ferreira Oliveira |
| author_facet | Alex Gonçalves Feitosa Yannice Tatiane da Costa Santos Jorge Marcell Coelho Menezes Henrique Douglas Melo Coutinho Victor Feitosa Teixeira João Hermínio da Silva Francisco José de Paula Filho Raimundo Nonato Pereira Teixeira Thiago Mielle Brito Ferreira Oliveira |
| author_sort | Alex Gonçalves Feitosa |
| collection | DOAJ |
| description | This work was carried out with the objective of studying the process of adsorption of Pb2+ ions by barley dust, Hordeum vulgare L. The adsorbent material was prepared by boiling in water with consequent sedimentation, drying, grinding and sieving. Kinetic, isothermal and thermodynamic studies were carried out in the adsorption processes. Factors such as contact time (1–128 min), initial concentration (20–400 mg.L-1) and temperature (288–298, 308 and 318 K) were considered. Mathematical models were applied and satisfactorily demonstrated the adsorptive process. The pseudo-first order models, pseudo-second order models Elovich and Boyd showed that equilibrium was reached within the first 40 min, with the pseudo-second order model as the most suitable to describe the process, as well as adsorption by external diffusion was demonstrated from the model of Boyd. The adsorption isotherm was evaluated using the Langmuir, Freundlich and Temkin models, demonstrating great applicability to the adsorptive process. The maximum adsorption capacity obtained in the Langmuir model was in the order of 25.76 mg.g−1. The Freundlich model indicated that the process is favorable. The thermodynamic parameters were calculated, demonstrating that the adsorption is endothermic and favorable. Therefore, the results obtained showed that the waste of roasted and ground barley powder can be used as an alternative, viable and low-cost adsorbent for use in processes aimed at decontaminating effluents containing Pb2+ ions. |
| first_indexed | 2024-03-09T01:28:56Z |
| format | Article |
| id | doaj.art-ff9d36a884f94ec0a5365381851f322e |
| institution | Directory Open Access Journal |
| issn | 2211-7156 |
| language | English |
| last_indexed | 2024-03-09T01:28:56Z |
| publishDate | 2023-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Chemistry |
| spelling | doaj.art-ff9d36a884f94ec0a5365381851f322e2023-12-10T06:15:37ZengElsevierResults in Chemistry2211-71562023-12-016101205Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) wasteAlex Gonçalves Feitosa0Yannice Tatiane da Costa Santos1Jorge Marcell Coelho Menezes2Henrique Douglas Melo Coutinho3Victor Feitosa Teixeira4João Hermínio da Silva5Francisco José de Paula Filho6Raimundo Nonato Pereira Teixeira7Thiago Mielle Brito Ferreira Oliveira8Science and Technology Center, Federal University of Cariri, BrazilFederal Institute of Education, Science and Technology of Ceará, BrazilScience and Technology Center, Federal University of Cariri, BrazilDepartment of Biological Chemistry, Regional University of Cariri, Brazil; Corresponding author.Department of Biological Chemistry, Regional University of Cariri, BrazilScience and Technology Center, Federal University of Cariri, BrazilScience and Technology Center, Federal University of Cariri, BrazilDepartment of Biological Chemistry, Regional University of Cariri, BrazilScience and Technology Center, Federal University of Cariri, BrazilThis work was carried out with the objective of studying the process of adsorption of Pb2+ ions by barley dust, Hordeum vulgare L. The adsorbent material was prepared by boiling in water with consequent sedimentation, drying, grinding and sieving. Kinetic, isothermal and thermodynamic studies were carried out in the adsorption processes. Factors such as contact time (1–128 min), initial concentration (20–400 mg.L-1) and temperature (288–298, 308 and 318 K) were considered. Mathematical models were applied and satisfactorily demonstrated the adsorptive process. The pseudo-first order models, pseudo-second order models Elovich and Boyd showed that equilibrium was reached within the first 40 min, with the pseudo-second order model as the most suitable to describe the process, as well as adsorption by external diffusion was demonstrated from the model of Boyd. The adsorption isotherm was evaluated using the Langmuir, Freundlich and Temkin models, demonstrating great applicability to the adsorptive process. The maximum adsorption capacity obtained in the Langmuir model was in the order of 25.76 mg.g−1. The Freundlich model indicated that the process is favorable. The thermodynamic parameters were calculated, demonstrating that the adsorption is endothermic and favorable. Therefore, the results obtained showed that the waste of roasted and ground barley powder can be used as an alternative, viable and low-cost adsorbent for use in processes aimed at decontaminating effluents containing Pb2+ ions.http://www.sciencedirect.com/science/article/pii/S2211715623004447AdsorptionHordeum vulgare L.LeadKineticsIsothermThermodynamics |
| spellingShingle | Alex Gonçalves Feitosa Yannice Tatiane da Costa Santos Jorge Marcell Coelho Menezes Henrique Douglas Melo Coutinho Victor Feitosa Teixeira João Hermínio da Silva Francisco José de Paula Filho Raimundo Nonato Pereira Teixeira Thiago Mielle Brito Ferreira Oliveira Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste Results in Chemistry Adsorption Hordeum vulgare L. Lead Kinetics Isotherm Thermodynamics |
| title | Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste |
| title_full | Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste |
| title_fullStr | Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste |
| title_full_unstemmed | Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste |
| title_short | Evaluation of Pb2+ ion adsorption by roasted and grounded barley (Hordeum vulgare L.) waste |
| title_sort | evaluation of pb2 ion adsorption by roasted and grounded barley hordeum vulgare l waste |
| topic | Adsorption Hordeum vulgare L. Lead Kinetics Isotherm Thermodynamics |
| url | http://www.sciencedirect.com/science/article/pii/S2211715623004447 |
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