Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Vasyl Stefanyk Precarpathian National University
2019-10-01
|
Series: | Фізика і хімія твердого тіла |
Subjects: | |
Online Access: | http://journals.pu.if.ua/index.php/pcss/article/view/3937 |
_version_ | 1830486879800131584 |
---|---|
author | L. P. Romaka Yu. V. Stadnyk V. A. Romaka A. M. Нoryn I. M. Romaniv V. Ya. Krayovskyy S. P. Dubelt |
author_facet | L. P. Romaka Yu. V. Stadnyk V. A. Romaka A. M. Нoryn I. M. Romaniv V. Ya. Krayovskyy S. P. Dubelt |
author_sort | L. P. Romaka |
collection | DOAJ |
description | The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073 K. The electrokinetic and energy state characteristics of the ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn semiconducting solid solution were investigated in the temperature range <em>T</em> = 80–400 K. An analysis of behavior of the electrokinetic and energetic characteristics, in particular, the motion rate of the Fermi level, Δ<em>ε</em><sub>F</sub>/Δ<em>x</em> for ZrNi<sub>1-<em>x</em></sub>V<em><sub>x</sub></em>Sn, allows to assume about the simultaneous generation of the structural defects of donor and acceptor nature in the crystal. The additional researches are required to establish the mechanisms of donor generation. |
first_indexed | 2024-12-21T18:50:54Z |
format | Article |
id | doaj.art-ffcf0160564240dda30afc25c604fa12 |
institution | Directory Open Access Journal |
issn | 1729-4428 2309-8589 |
language | English |
last_indexed | 2024-12-21T18:50:54Z |
publishDate | 2019-10-01 |
publisher | Vasyl Stefanyk Precarpathian National University |
record_format | Article |
series | Фізика і хімія твердого тіла |
spelling | doaj.art-ffcf0160564240dda30afc25c604fa122022-12-21T18:53:45ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892019-10-0120327528110.15330/pcss.20.3.275-2813252Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solutionL. P. Romaka0Yu. V. Stadnyk1V. A. Romaka2A. M. Нoryn3I. M. Romaniv4V. Ya. Krayovskyy5S. P. Dubelt6Львівський національний університет імені Івана ФранкаЛьвівський національний університет імені Івана ФранкаНаціональний університет “Львівська політехніка”Львівський національний університет імені Івана ФранкаЛьвівський національний університет імені Івана ФранкаНаціональний університет “Львівська політехніка”Національний університет “Львівська політехніка”The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073 K. The electrokinetic and energy state characteristics of the ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn semiconducting solid solution were investigated in the temperature range <em>T</em> = 80–400 K. An analysis of behavior of the electrokinetic and energetic characteristics, in particular, the motion rate of the Fermi level, Δ<em>ε</em><sub>F</sub>/Δ<em>x</em> for ZrNi<sub>1-<em>x</em></sub>V<em><sub>x</sub></em>Sn, allows to assume about the simultaneous generation of the structural defects of donor and acceptor nature in the crystal. The additional researches are required to establish the mechanisms of donor generation.http://journals.pu.if.ua/index.php/pcss/article/view/3937електропровідністькоефіцієнт термо-ерсрівень фермі. |
spellingShingle | L. P. Romaka Yu. V. Stadnyk V. A. Romaka A. M. Нoryn I. M. Romaniv V. Ya. Krayovskyy S. P. Dubelt Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution Фізика і хімія твердого тіла електропровідність коефіцієнт термо-ерс рівень фермі. |
title | Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution |
title_full | Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution |
title_fullStr | Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution |
title_full_unstemmed | Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution |
title_short | Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution |
title_sort | synthesis structural electrokinetic and energy state properties of zrni1 хvxsn solid solution |
topic | електропровідність коефіцієнт термо-ерс рівень фермі. |
url | http://journals.pu.if.ua/index.php/pcss/article/view/3937 |
work_keys_str_mv | AT lpromaka synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT yuvstadnyk synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT varomaka synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT amnoryn synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT imromaniv synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT vyakrayovskyy synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution AT spdubelt synthesisstructuralelectrokineticandenergystatepropertiesofzrni1hvxsnsolidsolution |