Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution

The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073...

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Main Authors: L. P. Romaka, Yu. V. Stadnyk, V. A. Romaka, A. M. Нoryn, I. M. Romaniv, V. Ya. Krayovskyy, S. P. Dubelt
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2019-10-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:http://journals.pu.if.ua/index.php/pcss/article/view/3937
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author L. P. Romaka
Yu. V. Stadnyk
V. A. Romaka
A. M. Нoryn
I. M. Romaniv
V. Ya. Krayovskyy
S. P. Dubelt
author_facet L. P. Romaka
Yu. V. Stadnyk
V. A. Romaka
A. M. Нoryn
I. M. Romaniv
V. Ya. Krayovskyy
S. P. Dubelt
author_sort L. P. Romaka
collection DOAJ
description The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073 K. The electrokinetic and energy state characteristics of the ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn semiconducting solid solution were investigated in the temperature range <em>T</em> = 80–400 K. An analysis of behavior of the electrokinetic and energetic characteristics, in particular, the motion rate of the Fermi level, Δ<em>ε</em><sub>F</sub>/Δ<em>x</em> for ZrNi<sub>1-<em>x</em></sub>V<em><sub>x</sub></em>Sn, allows to assume about the simultaneous generation of the structural defects of donor and acceptor nature in the crystal. The additional researches are required to establish the mechanisms of donor generation.
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spelling doaj.art-ffcf0160564240dda30afc25c604fa122022-12-21T18:53:45ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892019-10-0120327528110.15330/pcss.20.3.275-2813252Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solutionL. P. Romaka0Yu. V. Stadnyk1V. A. Romaka2A. M. Нoryn3I. M. Romaniv4V. Ya. Krayovskyy5S. P. Dubelt6Львівський національний університет імені Івана ФранкаЛьвівський національний університет імені Івана ФранкаНаціональний університет “Львівська політехніка”Львівський національний університет імені Івана ФранкаЛьвівський національний університет імені Івана ФранкаНаціональний університет “Львівська політехніка”Національний університет “Львівська політехніка”The samples of ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn solid solution (<em>x</em> = 0–0.10) based on the ZrNiSn half-Heusler phase (MgAgAs structure type) were synthesized by direct arc-melting with homogenous annealing at 1073 K. The electrokinetic and energy state characteristics of the ZrNi<sub>1-<em>х</em></sub>V<em><sub>x</sub></em>Sn semiconducting solid solution were investigated in the temperature range <em>T</em> = 80–400 K. An analysis of behavior of the electrokinetic and energetic characteristics, in particular, the motion rate of the Fermi level, Δ<em>ε</em><sub>F</sub>/Δ<em>x</em> for ZrNi<sub>1-<em>x</em></sub>V<em><sub>x</sub></em>Sn, allows to assume about the simultaneous generation of the structural defects of donor and acceptor nature in the crystal. The additional researches are required to establish the mechanisms of donor generation.http://journals.pu.if.ua/index.php/pcss/article/view/3937електропровідністькоефіцієнт термо-ерсрівень фермі.
spellingShingle L. P. Romaka
Yu. V. Stadnyk
V. A. Romaka
A. M. Нoryn
I. M. Romaniv
V. Ya. Krayovskyy
S. P. Dubelt
Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
Фізика і хімія твердого тіла
електропровідність
коефіцієнт термо-ерс
рівень фермі.
title Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
title_full Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
title_fullStr Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
title_full_unstemmed Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
title_short Synthesis, structural, electrokinetic and energy state properties of ZrNi1-хVxSn solid solution
title_sort synthesis structural electrokinetic and energy state properties of zrni1 хvxsn solid solution
topic електропровідність
коефіцієнт термо-ерс
рівень фермі.
url http://journals.pu.if.ua/index.php/pcss/article/view/3937
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