Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809013889 |
| Summary: | The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the CuII cations to form a two-dimensional polymeric layer. O—H...O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework. |
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| ISSN: | 1600-5368 |