Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809013889 |
| _version_ | 1818894279594999808 |
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| author | Qi-Hua Zhao Li-Nan Li Lin Du |
| author_facet | Qi-Hua Zhao Li-Nan Li Lin Du |
| author_sort | Qi-Hua Zhao |
| collection | DOAJ |
| description | The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the CuII cations to form a two-dimensional polymeric layer. O—H...O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework. |
| first_indexed | 2024-12-19T18:25:58Z |
| format | Article |
| id | doaj.art-fff34ce82a2941ad8f4f77907da62ba8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:25:58Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fff34ce82a2941ad8f4f77907da62ba82022-12-21T20:10:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m556m55610.1107/S1600536809013889Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]Qi-Hua ZhaoLi-Nan LiLin DuThe title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the CuII cations to form a two-dimensional polymeric layer. O—H...O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework.http://scripts.iucr.org/cgi-bin/paper?S1600536809013889 |
| spellingShingle | Qi-Hua Zhao Li-Nan Li Lin Du Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] Acta Crystallographica Section E |
| title | Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] |
| title_full | Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] |
| title_fullStr | Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] |
| title_full_unstemmed | Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] |
| title_short | Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)] |
| title_sort | poly diaqua amp 956 3 pyridine 3 5 dicarboxylato amp 954 3n o3 o5 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809013889 |
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