(2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate
The title dimethyl sulfoxide solvate, [Hg2(C12H9ClN2)I2]·C2H6OS, features tetrahedrally and linearly coordinated HgII atoms. The distorted tetrahedral coordination sphere is defined by chelating N atoms that define an acute angle [69.6 (3)°] and two I atoms that form a wi...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813029693 |
| _version_ | 1818322020910235648 |
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| author | Edward R. T. Tiekink Seik Weng Ng Imliwati Longkumer Tushar S. Basu Baul |
| author_facet | Edward R. T. Tiekink Seik Weng Ng Imliwati Longkumer Tushar S. Basu Baul |
| author_sort | Edward R. T. Tiekink |
| collection | DOAJ |
| description | The title dimethyl sulfoxide solvate, [Hg2(C12H9ClN2)I2]·C2H6OS, features tetrahedrally and linearly coordinated HgII atoms. The distorted tetrahedral coordination sphere is defined by chelating N atoms that define an acute angle [69.6 (3)°] and two I atoms that form a wide angle [142.80 (4)°]. The linearly coordinated HgII atom [177.0 (4)°] exists with a donor set defined by C and Cl atoms. Secondary interactions are apparent in the crystal packing with the tetrahedrally and linearly coordinated HgII atoms expanding their coordination environments by forming weak Hg...I [3.772 (7) Å] and Hg...O [2.921 (12) Å] interactions, respectively. Mercury-containing molecules stack along the a axis, are connected by π–π interactions [inter-centroid distance between pyridine and benzene rings = 3.772 (7) Å] and define channels in which the dimethyl sulfoxide molecules reside. The latter are connected by the aforementioned Hg...O interactions as well as C—H...I and C—H...O interactions, resulting in a three-dimensional architecture. |
| first_indexed | 2024-12-13T10:50:10Z |
| format | Article |
| id | doaj.art-fffd53827771472e949b8d649eb3f50f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:50:10Z |
| publishDate | 2013-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fffd53827771472e949b8d649eb3f50f2022-12-21T23:49:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m633m63410.1107/S1600536813029693(2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvateEdward R. T. TiekinkSeik Weng NgImliwati LongkumerTushar S. Basu BaulThe title dimethyl sulfoxide solvate, [Hg2(C12H9ClN2)I2]·C2H6OS, features tetrahedrally and linearly coordinated HgII atoms. The distorted tetrahedral coordination sphere is defined by chelating N atoms that define an acute angle [69.6 (3)°] and two I atoms that form a wide angle [142.80 (4)°]. The linearly coordinated HgII atom [177.0 (4)°] exists with a donor set defined by C and Cl atoms. Secondary interactions are apparent in the crystal packing with the tetrahedrally and linearly coordinated HgII atoms expanding their coordination environments by forming weak Hg...I [3.772 (7) Å] and Hg...O [2.921 (12) Å] interactions, respectively. Mercury-containing molecules stack along the a axis, are connected by π–π interactions [inter-centroid distance between pyridine and benzene rings = 3.772 (7) Å] and define channels in which the dimethyl sulfoxide molecules reside. The latter are connected by the aforementioned Hg...O interactions as well as C—H...I and C—H...O interactions, resulting in a three-dimensional architecture.http://scripts.iucr.org/cgi-bin/paper?S1600536813029693 |
| spellingShingle | Edward R. T. Tiekink Seik Weng Ng Imliwati Longkumer Tushar S. Basu Baul (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate Acta Crystallographica Section E |
| title | (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate |
| title_full | (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate |
| title_fullStr | (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate |
| title_full_unstemmed | (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate |
| title_short | (2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate |
| title_sort | 2 4 chloridomercuryl phenyl iminomethyl pyridine 954 2n n 8242 diiodidomercury ii dimethyl sulfoxide monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813029693 |
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