Chalcogenide glass materials for integrated infrared photonics

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2015.

Bibliographic Details
Main Author: Singh, Vivek, Ph. D. Massachusetts Institute of Technology
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering.
Format: Thesis
Language:eng
Published: Massachusetts Institute of Technology 2016
Subjects:
Online Access:http://hdl.handle.net/1721.1/101459
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author Singh, Vivek, Ph. D. Massachusetts Institute of Technology
author2 Massachusetts Institute of Technology. Department of Materials Science and Engineering.
author_facet Massachusetts Institute of Technology. Department of Materials Science and Engineering.
Singh, Vivek, Ph. D. Massachusetts Institute of Technology
author_sort Singh, Vivek, Ph. D. Massachusetts Institute of Technology
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description Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2015.
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spelling mit-1721.1/1014592019-04-11T01:00:22Z Chalcogenide glass materials for integrated infrared photonics Singh, Vivek, Ph. D. Massachusetts Institute of Technology Massachusetts Institute of Technology. Department of Materials Science and Engineering. Massachusetts Institute of Technology. Department of Materials Science and Engineering. Materials Science and Engineering. Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2015. This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. Cataloged from student-submitted PDF version of thesis. Includes bibliographical references (pages 181-198). Chalcogenide glasses (ChGs) are amorphous compounds containing the chalcogen elements (S, Se, Te) and exhibit wide infrared transparency windows. They are easy to synthesize in bulk and thin film forms and their compositional flexibility allows tuning of optical properties such as refractive index making them ideal for infrared photonics. We have studied the material attenuation in ChGs that arises due to the presence of impurities in the raw materials and established UV photolithography-based process flows that enable fabrication of chalcogenide glass waveguides and microresonators for near- and mid-IR wavelength ranges. Waveguides and optical resonators are key microphotonic elements for many on-chip applications such as telecommunications and chemical sensing. In this thesis, we show that scattering losses dominate in our ChG microphotonic devices while material attenuation from impurities is low. We demonstrate resonators coated with nanoporous polymers to improve their selectivity against target analytes for sensing applications. We exploit the photosensitivity of As2S3 glass to build silicon-based tunable photonic devices that offer post-fabrication tuning to optimize performance. Resonators also serve as a test platform for studying the effects of radiation on silicon and chalcogenide materials systems. Further, we propose new mid-IR microphotonic device designs using ChG materials and the challenges associated with measuring mid-IR devices along with solutions to address them. We employ input-to-output offsets, standard tapered waveguides, and a fiber collimator to improve mid-IR measurements and demonstrate transparent ChG waveguides with losses as low as 2.5 dB/cm. Finally, we propose a novel design that integrates PbTe detectors with ChG waveguides for on-chip mid-IR detection. Our simulations show that the use of a low-index spacer layer leads to a well-distributed field along the width of the detector due to a reduction in the effective index of the structure. We develop a fabrication process for waveguide-integrated detector designs and fabricate prototype structures that exhibit attenuation at telecom and mid-IR wavelengths. Such an integrated sensor design will enable the creation and deployment of low-cost remote sensor arrays with small footprints, and ultimately lead to "lab-on-a-chip" structures. by Vivek Singh. Ph. D. 2016-03-03T20:29:53Z 2016-03-03T20:29:53Z 2015 2015 Thesis http://hdl.handle.net/1721.1/101459 940569218 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 198 pages application/pdf Massachusetts Institute of Technology
spellingShingle Materials Science and Engineering.
Singh, Vivek, Ph. D. Massachusetts Institute of Technology
Chalcogenide glass materials for integrated infrared photonics
title Chalcogenide glass materials for integrated infrared photonics
title_full Chalcogenide glass materials for integrated infrared photonics
title_fullStr Chalcogenide glass materials for integrated infrared photonics
title_full_unstemmed Chalcogenide glass materials for integrated infrared photonics
title_short Chalcogenide glass materials for integrated infrared photonics
title_sort chalcogenide glass materials for integrated infrared photonics
topic Materials Science and Engineering.
url http://hdl.handle.net/1721.1/101459
work_keys_str_mv AT singhvivekphdmassachusettsinstituteoftechnology chalcogenideglassmaterialsforintegratedinfraredphotonics