On exergy calculations of seawater with applications in desalination systems

Exergy analysis is a powerful diagnostic tool in thermal systems performance evaluation. The use of such an analysis in seawater desalination processes is of growing importance to determine the sites of the highest irreversible losses. In the literature, exergy analyses of seawater desalination syst...

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Main Authors: Sharqawy, Mostafa H., Zubair, Syed M., Lienhard, John H
Other Authors: Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
Format: Article
Language:en_US
Published: Elsevier 2016
Online Access:http://hdl.handle.net/1721.1/101905
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0003-4777-1286
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author Sharqawy, Mostafa H.
Zubair, Syed M.
Lienhard, John H
author2 Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
author_facet Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
Sharqawy, Mostafa H.
Zubair, Syed M.
Lienhard, John H
author_sort Sharqawy, Mostafa H.
collection MIT
description Exergy analysis is a powerful diagnostic tool in thermal systems performance evaluation. The use of such an analysis in seawater desalination processes is of growing importance to determine the sites of the highest irreversible losses. In the literature, exergy analyses of seawater desalination systems have sometimes modeled seawater as sodium chloride solutions of equivalent salt content or salinity; however, such matching does not bring all important properties of the two solutions into agreement. Furthermore, a common model that represents seawater as an ideal mixture of liquid water and solid sodium chloride may have serious shortcomings. Therefore, in this paper, the most up-to-date thermodynamic properties of seawater, as needed to conduct an exergy analysis, are given as correlations and tabulated data. The effect of the system properties as well as the environment dead state on the exergy and flow exergy variation is investigated. In addition, an exergy analysis for a large MSF distillation plant is performed using plant operating data and results previously published using the above-mentioned ideal mixture model. It is demonstrated that this ideal mixture model gives flow exergy values that are far from the correct ones. Moreover, the second law efficiency differs by about 80% for some cases.
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spelling mit-1721.1/1019052025-02-25T15:29:29Z On exergy calculations of seawater with applications in desalination systems Sharqawy, Mostafa H. Zubair, Syed M. Lienhard, John H Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab Massachusetts Institute of Technology. Department of Mechanical Engineering Sharqawy, Mostafa H. Lienhard, John H. Exergy analysis is a powerful diagnostic tool in thermal systems performance evaluation. The use of such an analysis in seawater desalination processes is of growing importance to determine the sites of the highest irreversible losses. In the literature, exergy analyses of seawater desalination systems have sometimes modeled seawater as sodium chloride solutions of equivalent salt content or salinity; however, such matching does not bring all important properties of the two solutions into agreement. Furthermore, a common model that represents seawater as an ideal mixture of liquid water and solid sodium chloride may have serious shortcomings. Therefore, in this paper, the most up-to-date thermodynamic properties of seawater, as needed to conduct an exergy analysis, are given as correlations and tabulated data. The effect of the system properties as well as the environment dead state on the exergy and flow exergy variation is investigated. In addition, an exergy analysis for a large MSF distillation plant is performed using plant operating data and results previously published using the above-mentioned ideal mixture model. It is demonstrated that this ideal mixture model gives flow exergy values that are far from the correct ones. Moreover, the second law efficiency differs by about 80% for some cases. Center for Clean Water and Clean Energy at MIT and KFUPM 2016-03-29T17:18:56Z 2016-03-29T17:18:56Z 2010-11 2010-09 Article http://purl.org/eprint/type/JournalArticle 12900729 http://hdl.handle.net/1721.1/101905 Sharqawy, Mostafa H., John H. Lienhard V, and Syed M. Zubair. “On Exergy Calculations of Seawater with Applications in Desalination Systems.” International Journal of Thermal Sciences 50, no. 2 (February 2011): 187–196. https://orcid.org/0000-0002-2901-0638 https://orcid.org/0000-0003-4777-1286 en_US http://dx.doi.org/10.1016/j.ijthermalsci.2010.09.013 International Journal of Thermal Sciences Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf Elsevier Prof. Lienhard via Angie Locknar
spellingShingle Sharqawy, Mostafa H.
Zubair, Syed M.
Lienhard, John H
On exergy calculations of seawater with applications in desalination systems
title On exergy calculations of seawater with applications in desalination systems
title_full On exergy calculations of seawater with applications in desalination systems
title_fullStr On exergy calculations of seawater with applications in desalination systems
title_full_unstemmed On exergy calculations of seawater with applications in desalination systems
title_short On exergy calculations of seawater with applications in desalination systems
title_sort on exergy calculations of seawater with applications in desalination systems
url http://hdl.handle.net/1721.1/101905
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0003-4777-1286
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