Entropy generation in condensation in the presence of high concentrations of noncondensable gases

The physical mechanisms of entropy generation in a condenser with high fractions of noncondensable gases are examined using scaling and boundary layer techniques, with the aim of defining a criterion for minimum entropy generation rate that is useful in engineering analyses. This process is particul...

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Main Authors: Thiel, Gregory Parker, Lienhard, John H
Other Authors: Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
Format: Article
Language:en_US
Published: Elsevier 2016
Online Access:http://hdl.handle.net/1721.1/102078
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0002-4583-1057
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author Thiel, Gregory Parker
Lienhard, John H
author2 Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
author_facet Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
Thiel, Gregory Parker
Lienhard, John H
author_sort Thiel, Gregory Parker
collection MIT
description The physical mechanisms of entropy generation in a condenser with high fractions of noncondensable gases are examined using scaling and boundary layer techniques, with the aim of defining a criterion for minimum entropy generation rate that is useful in engineering analyses. This process is particularly relevant in humidification-dehumidification desalination systems, where minimizing entropy generation per unit water produced is critical to maximizing system performance. The process is modeled by a consideration of the vapor/gas boundary layer alone, as it is the dominant thermal resistance and, consequently, the largest source of entropy production in many practical condensers with high fractions of noncondensable gases. Most previous studies of condensation have been restricted to a constant wall temperature, but it is shown here that for high concentrations of noncondensable gases, a varying wall temperature greatly reduces total entropy generation rate. Further, it is found that the diffusion of the condensing vapor through the vapor/noncondensable mixture boundary layer is the larger and often dominant mechanism of entropy production in such a condenser. As a result, when seeking to design a unit of desired heat transfer and condensation rates for minimum entropy generation, minimizing the variance in the driving force associated with diffusion yields a closer approximation to the minimum overall entropy generation rate than does equipartition of temperature difference.
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spelling mit-1721.1/1020782023-02-17T02:05:29Z Entropy generation in condensation in the presence of high concentrations of noncondensable gases Thiel, Gregory Parker Lienhard, John H Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab Massachusetts Institute of Technology. Department of Mechanical Engineering Thiel, Gregory Parker Lienhard, John H. The physical mechanisms of entropy generation in a condenser with high fractions of noncondensable gases are examined using scaling and boundary layer techniques, with the aim of defining a criterion for minimum entropy generation rate that is useful in engineering analyses. This process is particularly relevant in humidification-dehumidification desalination systems, where minimizing entropy generation per unit water produced is critical to maximizing system performance. The process is modeled by a consideration of the vapor/gas boundary layer alone, as it is the dominant thermal resistance and, consequently, the largest source of entropy production in many practical condensers with high fractions of noncondensable gases. Most previous studies of condensation have been restricted to a constant wall temperature, but it is shown here that for high concentrations of noncondensable gases, a varying wall temperature greatly reduces total entropy generation rate. Further, it is found that the diffusion of the condensing vapor through the vapor/noncondensable mixture boundary layer is the larger and often dominant mechanism of entropy production in such a condenser. As a result, when seeking to design a unit of desired heat transfer and condensation rates for minimum entropy generation, minimizing the variance in the driving force associated with diffusion yields a closer approximation to the minimum overall entropy generation rate than does equipartition of temperature difference. Center for Clean Water and Clean Energy at MIT and KFUPM (Project R4-CW-08) Eni S.p.A. (Firm) (Eni-MIT Energy Fellowship) 2016-04-01T17:42:39Z 2016-04-01T17:42:39Z 2012-05 2012-04 Article http://purl.org/eprint/type/JournalArticle 00179310 http://hdl.handle.net/1721.1/102078 Thiel, Gregory P., and John H. Lienhard. “Entropy Generation in Condensation in the Presence of High Concentrations of Noncondensable Gases.” International Journal of Heat and Mass Transfer 55, no. 19–20 (September 2012): 5133–5147. https://orcid.org/0000-0002-2901-0638 https://orcid.org/0000-0002-4583-1057 en_US http://dx.doi.org/10.1016/j.ijheatmasstransfer.2012.05.014 International Journal of Heat and Mass Transfer Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf Elsevier Prof. Lienhard via Angie Locknar
spellingShingle Thiel, Gregory Parker
Lienhard, John H
Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title_full Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title_fullStr Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title_full_unstemmed Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title_short Entropy generation in condensation in the presence of high concentrations of noncondensable gases
title_sort entropy generation in condensation in the presence of high concentrations of noncondensable gases
url http://hdl.handle.net/1721.1/102078
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0002-4583-1057
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