Variational approach to extracting the phonon mean free path distribution from the spectral Boltzmann transport equation

The phonon Boltzmann transport equation (BTE) is a powerful tool for studying nondiffusive thermal transport. Here, we develop a new universal variational approach to solving the BTE that enables extraction of phonon mean free path (MFP) distributions from experiments exploring nondiffusive transpor...

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Bibliographic Details
Main Authors: Chiloyan, Vazrik, Zeng, Lingping, Chen, Gang, Huberman, Samuel C., Maznev, Alexei, Nelson, Keith Adam
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: American Physical Society 2016
Online Access:http://hdl.handle.net/1721.1/102228
https://orcid.org/0000-0002-2145-0890
https://orcid.org/0000-0001-8051-5378
https://orcid.org/0000-0003-0865-8096
https://orcid.org/0000-0002-3968-8530
https://orcid.org/0000-0001-7804-5418
Description
Summary:The phonon Boltzmann transport equation (BTE) is a powerful tool for studying nondiffusive thermal transport. Here, we develop a new universal variational approach to solving the BTE that enables extraction of phonon mean free path (MFP) distributions from experiments exploring nondiffusive transport. By utilizing the known Fourier heat conduction solution as a trial function, we present a direct approach to calculating the effective thermal conductivity from the BTE. We demonstrate this technique on the transient thermal grating experiment, which is a useful tool for studying nondiffusive thermal transport and probing the MFP distribution of materials. We obtain a closed form expression for a suppression function that is materials dependent, successfully addressing the nonuniversality of the suppression function used in the past, while providing a general approach to studying thermal properties in the nondiffusive regime.