Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis

In many forward osmosis applications, flux is maximised (and capital costs minimised) when the membrane is oriented such that the feed solution faces the support layer (PRO mode). Here, a framework is developed to understand the factors that determine the membrane orientation that maximises flux. In...

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Main Authors: McGovern, Ronan Killian, Mizerak, Jordan P., Zubair, Syed M., Lienhard, John H
Other Authors: Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
Format: Article
Language:en_US
Published: Elsevier 2016
Online Access:http://hdl.handle.net/1721.1/102360
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0002-8338-4841
https://orcid.org/0000-0002-3808-8824
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author McGovern, Ronan Killian
Mizerak, Jordan P.
Zubair, Syed M.
Lienhard, John H
author2 Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
author_facet Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab
McGovern, Ronan Killian
Mizerak, Jordan P.
Zubair, Syed M.
Lienhard, John H
author_sort McGovern, Ronan Killian
collection MIT
description In many forward osmosis applications, flux is maximised (and capital costs minimised) when the membrane is oriented such that the feed solution faces the support layer (PRO mode). Here, a framework is developed to understand the factors that determine the membrane orientation that maximises flux. In the absence of fouling, a dimensionless form of the water transport equations reveals the importance of three dimensionless groups: the ratio of draw to feed osmotic pressure, the ratio of draw to feed solute diffusivity, and the resistance to water transport of the support layer relative to the active layer. A parametric study of these parameters and an application of the dimensionless equations to three important FO processes reveal that having the draw solution face the support layer (FO mode) can maximise flux in specific instances. Interestingly, this implies that operation in FO mode can both maximise flux and minimise fouling for fertigation applications and the concentration of flowback waters from hydraulic fracturing.
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spelling mit-1721.1/1023602023-02-17T02:05:36Z Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis McGovern, Ronan Killian Mizerak, Jordan P. Zubair, Syed M. Lienhard, John H Massachusetts Institute of Technology. Abdul Latif Jameel World Water & Food Security Lab Massachusetts Institute of Technology. Department of Mechanical Engineering McGovern, Ronan Killian Mizerak, Jordan P. Lienhard, John H. In many forward osmosis applications, flux is maximised (and capital costs minimised) when the membrane is oriented such that the feed solution faces the support layer (PRO mode). Here, a framework is developed to understand the factors that determine the membrane orientation that maximises flux. In the absence of fouling, a dimensionless form of the water transport equations reveals the importance of three dimensionless groups: the ratio of draw to feed osmotic pressure, the ratio of draw to feed solute diffusivity, and the resistance to water transport of the support layer relative to the active layer. A parametric study of these parameters and an application of the dimensionless equations to three important FO processes reveal that having the draw solution face the support layer (FO mode) can maximise flux in specific instances. Interestingly, this implies that operation in FO mode can both maximise flux and minimise fouling for fertigation applications and the concentration of flowback waters from hydraulic fracturing. Center for Clean Water and Clean Energy at MIT and KFUPM (Project R15-CW-11) United States. Dept. of State. Fulbright Science & Technology Program International Desalination Association (Channabasappa Memorial Scholarship) MIT Martin Family Society of Fellows for Sustainability Hugh Hampton Young Memorial Fellowship 2016-05-02T23:28:02Z 2016-05-02T23:28:02Z 2014-02 2014-01 Article http://purl.org/eprint/type/JournalArticle 03767388 http://hdl.handle.net/1721.1/102360 McGovern, Ronan K., Jordan P. Mizerak, Syed M. Zubair, and John H. Lienhard V. “Three Dimensionless Parameters Influencing the Optimal Membrane Orientation for Forward Osmosis.” Journal of Membrane Science 458 (May 2014): 104–110. https://orcid.org/0000-0002-2901-0638 https://orcid.org/0000-0002-8338-4841 https://orcid.org/0000-0002-3808-8824 en_US http://dx.doi.org/10.1016/j.memsci.2014.01.061 Journal of Membrane Science Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf Elsevier Prof. Lienhard via Angie Locknar
spellingShingle McGovern, Ronan Killian
Mizerak, Jordan P.
Zubair, Syed M.
Lienhard, John H
Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title_full Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title_fullStr Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title_full_unstemmed Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title_short Three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
title_sort three dimensionless parameters influencing the optimal membrane orientation for forward osmosis
url http://hdl.handle.net/1721.1/102360
https://orcid.org/0000-0002-2901-0638
https://orcid.org/0000-0002-8338-4841
https://orcid.org/0000-0002-3808-8824
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