New Pathways for Formation of Acids and Carbonyl Products in Low-Temperature Oxidation: The Korcek Decomposition of γ-Ketohydroperoxides

We present new reaction pathways relevant to low-temperature oxidation in gaseous and condensed phases. The new pathways originate from γ-ketohydroperoxides (KHP), which are well-known products in low-temperature oxidation and are assumed to react only via homolytic O–O dissociation in existing kine...

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Bibliographic Details
Main Authors: Meana-Pañeda, Rubén, Yang, Ke R., Truhlar, Donald G., Jalan, Amrit, Alecu, Ionut M, Aguilera Iparraguirre, Jorge, Merchant, Shamel S., Green, William H
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2017
Online Access:http://hdl.handle.net/1721.1/106967