Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors
Thesis: S.M., Massachusetts Institute of Technology, Department of Chemistry, 2016.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2017
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| Online Access: | http://hdl.handle.net/1721.1/107571 |
| _version_ | 1811083556324114432 |
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| author | Tanaset, Anont |
| author2 | Jeffrey F. Van Humbeck. |
| author_facet | Jeffrey F. Van Humbeck. Tanaset, Anont |
| author_sort | Tanaset, Anont |
| collection | MIT |
| description | Thesis: S.M., Massachusetts Institute of Technology, Department of Chemistry, 2016. |
| first_indexed | 2024-09-23T12:34:56Z |
| format | Thesis |
| id | mit-1721.1/107571 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T12:34:56Z |
| publishDate | 2017 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/1075712019-04-12T21:43:53Z Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors Tanaset, Anont Jeffrey F. Van Humbeck. Massachusetts Institute of Technology. Department of Chemistry. Massachusetts Institute of Technology. Department of Chemistry. Chemistry. Thesis: S.M., Massachusetts Institute of Technology, Department of Chemistry, 2016. Cataloged from PDF version of thesis. Includes bibliographical references. Porous aromatic frameworks (PAFs) have recently emerged as a new class of materials with impressive stability and high surface area, which led to their applications in gas storage and small molecule recognition. Herein, the synthesis and functionalization of PAFs were described, and their potential use as selective oligomerization for fuel upgrading was investigated. However, functionalized PAFs showed undesired reactivity possibly due to low rate of substrate and product diffusion in and out of the framework. On the other hand, a novel C3-symmetric hydrogen bonding receptor was synthesized and investigated for its use as size- and regioselective catalyst. It was demonstrated that the receptor was able to distinguish substrates with different functional groups in binding experiments, and was able to improve SN2 reaction yield although with some significant limitations. by Anont Tanaset. S.M. 2017-03-20T19:40:37Z 2017-03-20T19:40:37Z 2016 2016 Thesis http://hdl.handle.net/1721.1/107571 974642540 eng MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission. http://dspace.mit.edu/handle/1721.1/7582 70 pages application/pdf Massachusetts Institute of Technology |
| spellingShingle | Chemistry. Tanaset, Anont Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title | Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title_full | Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title_fullStr | Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title_full_unstemmed | Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title_short | Regio- and size-selective catalysis : porous aromatic frameworks and C3-symmetric receptors |
| title_sort | regio and size selective catalysis porous aromatic frameworks and c3 symmetric receptors |
| topic | Chemistry. |
| url | http://hdl.handle.net/1721.1/107571 |
| work_keys_str_mv | AT tanasetanont regioandsizeselectivecatalysisporousaromaticframeworksandc3symmetricreceptors |