Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine
Partially reduced graphene oxide (prGO) was covalently functionalized with a zwitterionic polymer polyzwitterionic polymer to afford a composite material with excellent dispersibility and long-term stability in high salinity brines including standard API and Arab-D found in deep oil reservoirs. When...
| Main Authors: | , , , |
|---|---|
| Drugi avtorji: | |
| Format: | Article |
| Jezik: | en_US |
| Izdano: |
American Chemical Society (ACS)
2017
|
| Online dostop: | http://hdl.handle.net/1721.1/107983 |
| _version_ | 1826190859418206208 |
|---|---|
| author | Cox, Jason R. Zuniga, Carlos A. Goods, John Benjamin Swager, Timothy M |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Cox, Jason R. Zuniga, Carlos A. Goods, John Benjamin Swager, Timothy M |
| author_sort | Cox, Jason R. |
| collection | MIT |
| description | Partially reduced graphene oxide (prGO) was covalently functionalized with a zwitterionic polymer polyzwitterionic polymer to afford a composite material with excellent dispersibility and long-term stability in high salinity brines including standard API and Arab-D found in deep oil reservoirs. When heated at 90 °C, the dispersions remained stable in excess of 140 days. These results suggest the utility of imidazolium-based polymers for brine stabilization as well as the use of diazonium containing polymers for a “grafting-to” approach to nanocarbon functionalization. |
| first_indexed | 2024-09-23T08:46:25Z |
| format | Article |
| id | mit-1721.1/107983 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T08:46:25Z |
| publishDate | 2017 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1079832022-09-23T14:28:34Z Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine Cox, Jason R. Zuniga, Carlos A. Goods, John Benjamin Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M. Zuniga, Carlos A. Goods, John Benjamin Swager, Timothy M Partially reduced graphene oxide (prGO) was covalently functionalized with a zwitterionic polymer polyzwitterionic polymer to afford a composite material with excellent dispersibility and long-term stability in high salinity brines including standard API and Arab-D found in deep oil reservoirs. When heated at 90 °C, the dispersions remained stable in excess of 140 days. These results suggest the utility of imidazolium-based polymers for brine stabilization as well as the use of diazonium containing polymers for a “grafting-to” approach to nanocarbon functionalization. Saudi Aramco (MIT Energy Initiative) Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies Camille & Henry Dreyfus Foundation. Postdoctoral Program in Environmental Chemistry (Fellowship) 2017-04-07T20:54:31Z 2017-04-07T20:54:31Z 2016-01 2015-10 Article http://purl.org/eprint/type/JournalArticle 1944-8244 1944-8252 http://hdl.handle.net/1721.1/107983 Zuniga, Carlos A., John B. Goods, Jason R. Cox, and Timothy M. Swager. “Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine.” ACS Applied Materials & Interfaces 8, no. 3 (January 27, 2016): 1780–1785. en_US http://dx.doi.org/10.1021/acsami.5b09656 ACS Applied Materials & Interfaces Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Swager via Erja Kajosalo |
| spellingShingle | Cox, Jason R. Zuniga, Carlos A. Goods, John Benjamin Swager, Timothy M Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title | Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title_full | Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title_fullStr | Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title_full_unstemmed | Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title_short | Long-Term High-Temperature Stability of Functionalized Graphene Oxide Nanoplatelets in Arab-D and API Brine |
| title_sort | long term high temperature stability of functionalized graphene oxide nanoplatelets in arab d and api brine |
| url | http://hdl.handle.net/1721.1/107983 |
| work_keys_str_mv | AT coxjasonr longtermhightemperaturestabilityoffunctionalizedgrapheneoxidenanoplateletsinarabdandapibrine AT zunigacarlosa longtermhightemperaturestabilityoffunctionalizedgrapheneoxidenanoplateletsinarabdandapibrine AT goodsjohnbenjamin longtermhightemperaturestabilityoffunctionalizedgrapheneoxidenanoplateletsinarabdandapibrine AT swagertimothym longtermhightemperaturestabilityoffunctionalizedgrapheneoxidenanoplateletsinarabdandapibrine |