Thermoelectric Energy Conversion: Materials, Devices, and Systems

This paper will present a discussion of challenges, progresses, and opportunities in thermoelectric energy conversion technology. We will start with an introduction to thermoelectric technology, followed by discussing advances in thermoelectric materials, devices, and systems. Thermoelectric energy...

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Main Author: Chen, Gang
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:en_US
Published: IOP Publishing 2017
Online Access:http://hdl.handle.net/1721.1/108184
https://orcid.org/0000-0002-3968-8530
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author Chen, Gang
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Chen, Gang
author_sort Chen, Gang
collection MIT
description This paper will present a discussion of challenges, progresses, and opportunities in thermoelectric energy conversion technology. We will start with an introduction to thermoelectric technology, followed by discussing advances in thermoelectric materials, devices, and systems. Thermoelectric energy conversion exploits the Seebeck effect to convert thermal energy into electricity, or the Peltier effect for heat pumping applications. Thermoelectric devices are scalable, capable of generating power from nano Watts to mega Watts. One key issue is to improve materials thermoelectric figure- of-merit that is linearly proportional to the Seebeck coefficient, the square of the electrical conductivity, and inversely proportional to the thermal conductivity. Improving the figure-of-merit requires good understanding of electron and phonon transport as their properties are often contradictory in trends. Over the past decade, excellent progresses have been made in the understanding of electron and phonon transport in thermoelectric materials, and in improving existing and identify new materials, especially by exploring nanoscale size effects. Taking materials to real world applications, however, faces more challenges in terms of materials stability, device fabrication, thermal management and system design. Progresses and lessons learnt from our effort in fabricating thermoelectric devices will be discussed. We have demonstrated device thermal-to-electrical energy conversion efficiency ~10% and solar-thermoelectric generator efficiency at 4.6% without optical concentration of sunlight (Figure 1) and ~8-9% efficiency with optical concentration. Great opportunities exist in advancing materials as well as in using existing materials for energy efficiency improvements and renewable energy utilization, as well as mobile applications.
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spelling mit-1721.1/1081842022-09-23T12:06:18Z Thermoelectric Energy Conversion: Materials, Devices, and Systems Chen, Gang Massachusetts Institute of Technology. Department of Mechanical Engineering Chen, Gang This paper will present a discussion of challenges, progresses, and opportunities in thermoelectric energy conversion technology. We will start with an introduction to thermoelectric technology, followed by discussing advances in thermoelectric materials, devices, and systems. Thermoelectric energy conversion exploits the Seebeck effect to convert thermal energy into electricity, or the Peltier effect for heat pumping applications. Thermoelectric devices are scalable, capable of generating power from nano Watts to mega Watts. One key issue is to improve materials thermoelectric figure- of-merit that is linearly proportional to the Seebeck coefficient, the square of the electrical conductivity, and inversely proportional to the thermal conductivity. Improving the figure-of-merit requires good understanding of electron and phonon transport as their properties are often contradictory in trends. Over the past decade, excellent progresses have been made in the understanding of electron and phonon transport in thermoelectric materials, and in improving existing and identify new materials, especially by exploring nanoscale size effects. Taking materials to real world applications, however, faces more challenges in terms of materials stability, device fabrication, thermal management and system design. Progresses and lessons learnt from our effort in fabricating thermoelectric devices will be discussed. We have demonstrated device thermal-to-electrical energy conversion efficiency ~10% and solar-thermoelectric generator efficiency at 4.6% without optical concentration of sunlight (Figure 1) and ~8-9% efficiency with optical concentration. Great opportunities exist in advancing materials as well as in using existing materials for energy efficiency improvements and renewable energy utilization, as well as mobile applications. 2017-04-14T19:37:49Z 2017-04-14T19:37:49Z 2015-12 2015-11 Article http://purl.org/eprint/type/JournalArticle 1742-6588 1742-6596 http://hdl.handle.net/1721.1/108184 Chen, Gang. “Thermoelectric Energy Conversion: Materials, Devices, and Systems.” Journal of Physics: Conference Series 660 (December 10, 2015): 012066. https://orcid.org/0000-0002-3968-8530 en_US http://dx.doi.org/10.1088/1742-6596/660/1/012066 Journal of Physics: Conference Series Creative Commons Attribution 3.0 Unported license http://creativecommons.org/licenses/by/3.0/ application/pdf IOP Publishing IOP Publishing
spellingShingle Chen, Gang
Thermoelectric Energy Conversion: Materials, Devices, and Systems
title Thermoelectric Energy Conversion: Materials, Devices, and Systems
title_full Thermoelectric Energy Conversion: Materials, Devices, and Systems
title_fullStr Thermoelectric Energy Conversion: Materials, Devices, and Systems
title_full_unstemmed Thermoelectric Energy Conversion: Materials, Devices, and Systems
title_short Thermoelectric Energy Conversion: Materials, Devices, and Systems
title_sort thermoelectric energy conversion materials devices and systems
url http://hdl.handle.net/1721.1/108184
https://orcid.org/0000-0002-3968-8530
work_keys_str_mv AT chengang thermoelectricenergyconversionmaterialsdevicesandsystems