Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation
The chemical vapor deposition (CVD) polymerization of metalloporphyrin building units is demonstrated to provide an easily up-scalable one-step method toward the deposition of a new class of dense and defect-free metal–organic covalent network (MOCN) layers. The resulting hyper-thin and flexible MOC...
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Format: | Article |
Language: | en_US |
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Wiley Blackwell
2017
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Online Access: | http://hdl.handle.net/1721.1/108287 https://orcid.org/0000-0003-2609-4204 https://orcid.org/0000-0001-6127-1056 |
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author | Perrotta, Alberto Heinze, Katja Creatore, Mariadriana Boscher, Nicolas Wang, Minghui Gleason, Karen K |
author2 | Massachusetts Institute of Technology. Department of Chemical Engineering |
author_facet | Massachusetts Institute of Technology. Department of Chemical Engineering Perrotta, Alberto Heinze, Katja Creatore, Mariadriana Boscher, Nicolas Wang, Minghui Gleason, Karen K |
author_sort | Perrotta, Alberto |
collection | MIT |
description | The chemical vapor deposition (CVD) polymerization of metalloporphyrin building units is demonstrated to provide an easily up-scalable one-step method toward the deposition of a new class of dense and defect-free metal–organic covalent network (MOCN) layers. The resulting hyper-thin and flexible MOCN layers exhibit outstanding gas-separation performances for multiple gas pairs. |
first_indexed | 2024-09-23T08:09:40Z |
format | Article |
id | mit-1721.1/108287 |
institution | Massachusetts Institute of Technology |
language | en_US |
last_indexed | 2024-09-23T08:09:40Z |
publishDate | 2017 |
publisher | Wiley Blackwell |
record_format | dspace |
spelling | mit-1721.1/1082872022-09-30T07:59:29Z Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation Perrotta, Alberto Heinze, Katja Creatore, Mariadriana Boscher, Nicolas Wang, Minghui Gleason, Karen K Massachusetts Institute of Technology. Department of Chemical Engineering Gleason, Karen K. Boscher, Nicolas Wang, Minghui Gleason, Karen K The chemical vapor deposition (CVD) polymerization of metalloporphyrin building units is demonstrated to provide an easily up-scalable one-step method toward the deposition of a new class of dense and defect-free metal–organic covalent network (MOCN) layers. The resulting hyper-thin and flexible MOCN layers exhibit outstanding gas-separation performances for multiple gas pairs. United States. Army Research Office. Institute for Soldier Nanotechnologies (Contract DAAD-19-02D-0002) Luxembourg National Research Fund 2017-04-20T15:14:55Z 2017-04-20T15:14:55Z 2016-09 2016-05 Article http://purl.org/eprint/type/JournalArticle 0935-9648 1521-4095 http://hdl.handle.net/1721.1/108287 Boscher, Nicolas D. et al. “Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation.” Advanced Materials 28.34 (2016): 7479–7485. https://orcid.org/0000-0003-2609-4204 https://orcid.org/0000-0001-6127-1056 en_US http://dx.doi.org/10.1002/adma.201601010 Advanced Materials Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Wiley Blackwell Prof. Gleason |
spellingShingle | Perrotta, Alberto Heinze, Katja Creatore, Mariadriana Boscher, Nicolas Wang, Minghui Gleason, Karen K Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title | Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title_full | Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title_fullStr | Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title_full_unstemmed | Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title_short | Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation |
title_sort | metal organic covalent network chemical vapor deposition for gas separation |
url | http://hdl.handle.net/1721.1/108287 https://orcid.org/0000-0003-2609-4204 https://orcid.org/0000-0001-6127-1056 |
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