One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent
A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is made in a one-pot synthesis using a rationally designed organic structure-directing agent (OSDA). The OSDA consists of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM-22(P), a hydr...
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| Format: | Article |
| Language: | en_US |
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Royal Society of Chemistry
2017
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| Online Access: | http://hdl.handle.net/1721.1/109310 https://orcid.org/0000-0001-5985-3348 https://orcid.org/0000-0002-6708-7660 https://orcid.org/0000-0003-1589-832X |
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| author | Luo, Helen Y Michaelis, Vladimir K. Hodges, Sydney E. Griffin, Robert Guy Roman-Leshkov, Yuriy |
| author2 | Massachusetts Institute of Technology. Department of Chemical Engineering |
| author_facet | Massachusetts Institute of Technology. Department of Chemical Engineering Luo, Helen Y Michaelis, Vladimir K. Hodges, Sydney E. Griffin, Robert Guy Roman-Leshkov, Yuriy |
| author_sort | Luo, Helen Y |
| collection | MIT |
| description | A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is made in a one-pot synthesis using a rationally designed organic structure-directing agent (OSDA). The OSDA consists of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM-22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM-22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m[superscript 2] g[superscript −1], and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. Compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel–Crafts alkylation of benzene with benzyl alcohol. |
| first_indexed | 2024-09-23T11:12:51Z |
| format | Article |
| id | mit-1721.1/109310 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T11:12:51Z |
| publishDate | 2017 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | mit-1721.1/1093102022-10-01T02:06:29Z One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent Luo, Helen Y Michaelis, Vladimir K. Hodges, Sydney E. Griffin, Robert Guy Roman-Leshkov, Yuriy Massachusetts Institute of Technology. Department of Chemical Engineering Massachusetts Institute of Technology. Department of Chemistry Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) Luo, Helen Y Michaelis, Vladimir K. Hodges, Sydney E. Griffin, Robert Guy Roman-Leshkov, Yuriy A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is made in a one-pot synthesis using a rationally designed organic structure-directing agent (OSDA). The OSDA consists of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM-22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM-22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m[superscript 2] g[superscript −1], and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. Compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel–Crafts alkylation of benzene with benzyl alcohol. United States. Dept. of Energy. Office of Basic Energy Sciences. Chemical Sciences, Geosciences, & Biosciences Division (DE-FG0212ER16352) Natural Sciences and Engineering Research Council of Canada (Banting Postdoctoral Fellowship) 2017-05-24T18:06:49Z 2017-05-24T18:06:49Z 2015-06 2015-05 Article http://purl.org/eprint/type/JournalArticle 2041-6520 2041-6539 http://hdl.handle.net/1721.1/109310 Luo, Helen Y. et al. “One-Pot Synthesis of MWW Zeolite Nanosheets Using a Rationally Designed Organic Structure-Directing Agent.” Chem. Sci. 6.11 (2015): 6320–6324. https://orcid.org/0000-0001-5985-3348 https://orcid.org/0000-0002-6708-7660 https://orcid.org/0000-0003-1589-832X en_US http://dx.doi.org/10.1039/C5SC01912E Chemical Science Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Royal Society of Chemistry PMC |
| spellingShingle | Luo, Helen Y Michaelis, Vladimir K. Hodges, Sydney E. Griffin, Robert Guy Roman-Leshkov, Yuriy One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title | One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title_full | One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title_fullStr | One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title_full_unstemmed | One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title_short | One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent |
| title_sort | one pot synthesis of mww zeolite nanosheets using a rationally designed organic structure directing agent |
| url | http://hdl.handle.net/1721.1/109310 https://orcid.org/0000-0001-5985-3348 https://orcid.org/0000-0002-6708-7660 https://orcid.org/0000-0003-1589-832X |
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