Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature
We describe the red phosphorescence exhibited by a class of structurally simple benzo[2,1,3]thiadiazoles at room temperature. The photophysical properties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-state photoluminescence and excitation spectra, and ph...
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| Format: | Article |
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American Chemical Society (ACS)
2017
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| Online Access: | http://hdl.handle.net/1721.1/109933 https://orcid.org/0000-0002-6027-042X https://orcid.org/0000-0003-2055-0475 https://orcid.org/0000-0003-3005-9831 https://orcid.org/0000-0003-2201-5257 |
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| author | Gutierrez, Gregory D. Sazama, Graham T. Wu, Tony C Baldo, Marc A Swager, Timothy M |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Gutierrez, Gregory D. Sazama, Graham T. Wu, Tony C Baldo, Marc A Swager, Timothy M |
| author_sort | Gutierrez, Gregory D. |
| collection | MIT |
| description | We describe the red phosphorescence exhibited by a class of structurally simple benzo[2,1,3]thiadiazoles at room temperature. The photophysical properties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-state photoluminescence and excitation spectra, and phosphorescence lifetimes, are presented. Time-dependent density functional theory calculations were carried out to better understand the electronic excited states of these benzo[2,1,3]thiadiazoles and why they are capable of phosphorescence. |
| first_indexed | 2024-09-23T15:39:25Z |
| format | Article |
| id | mit-1721.1/109933 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T15:39:25Z |
| publishDate | 2017 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1099332022-10-02T03:11:22Z Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature Gutierrez, Gregory D. Sazama, Graham T. Wu, Tony C Baldo, Marc A Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Gutierrez, Gregory D. Sazama, Graham T. Wu, Tony C Baldo, Marc A Swager, Timothy M We describe the red phosphorescence exhibited by a class of structurally simple benzo[2,1,3]thiadiazoles at room temperature. The photophysical properties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-state photoluminescence and excitation spectra, and phosphorescence lifetimes, are presented. Time-dependent density functional theory calculations were carried out to better understand the electronic excited states of these benzo[2,1,3]thiadiazoles and why they are capable of phosphorescence. National Science Foundation (U.S.) (1122374) United States. Dept. of Energy. Office of Basic Energy Sciences (DE-FG02-07ER46474) 2017-06-16T13:41:13Z 2017-06-16T13:41:13Z 2016-06 2016-04 Article http://purl.org/eprint/type/JournalArticle 0022-3263 1520-6904 http://hdl.handle.net/1721.1/109933 Gutierrez, Gregory D., Graham T. Sazama, Tony Wu, Marc A. Baldo, and Timothy M. Swager. “Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature.” The Journal of Organic Chemistry 81, no. 11 (June 3, 2016): 4789–4796. doi:10.1021/acs.joc.6b00789. https://orcid.org/0000-0002-6027-042X https://orcid.org/0000-0003-2055-0475 https://orcid.org/0000-0003-3005-9831 https://orcid.org/0000-0003-2201-5257 en_US http://dx.doi.org/10.1021/acs.joc.6b00789 The Journal of Organic Chemistry Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) PMC |
| spellingShingle | Gutierrez, Gregory D. Sazama, Graham T. Wu, Tony C Baldo, Marc A Swager, Timothy M Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title | Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title_full | Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title_fullStr | Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title_full_unstemmed | Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title_short | Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature |
| title_sort | red phosphorescence from benzo 2 1 3 thiadiazoles at room temperature |
| url | http://hdl.handle.net/1721.1/109933 https://orcid.org/0000-0002-6027-042X https://orcid.org/0000-0003-2055-0475 https://orcid.org/0000-0003-3005-9831 https://orcid.org/0000-0003-2201-5257 |
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