Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation

The evaporation of a liquid drop on a solid substrate is a remarkably common phenomenon. Yet, the complexity of the underlying mechanisms has constrained previous studies to spherically symmetric configurations. Here we investigate well-defined, non-spherical evaporating drops of pure liquids and bi...

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Main Authors: Wray, A. W., Che, Z., Matar, O. K., Valluri, P., Kim, J., Sefiane, K., Saenz Hervias, Pedro Javier
Other Authors: Massachusetts Institute of Technology. Department of Mathematics
Format: Article
Language:en_US
Published: Nature Publishing Group 2017
Online Access:http://hdl.handle.net/1721.1/110123
https://orcid.org/0000-0002-9130-3589
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author Wray, A. W.
Che, Z.
Matar, O. K.
Valluri, P.
Kim, J.
Sefiane, K.
Saenz Hervias, Pedro Javier
author2 Massachusetts Institute of Technology. Department of Mathematics
author_facet Massachusetts Institute of Technology. Department of Mathematics
Wray, A. W.
Che, Z.
Matar, O. K.
Valluri, P.
Kim, J.
Sefiane, K.
Saenz Hervias, Pedro Javier
author_sort Wray, A. W.
collection MIT
description The evaporation of a liquid drop on a solid substrate is a remarkably common phenomenon. Yet, the complexity of the underlying mechanisms has constrained previous studies to spherically symmetric configurations. Here we investigate well-defined, non-spherical evaporating drops of pure liquids and binary mixtures. We deduce a universal scaling law for the evaporation rate valid for any shape and demonstrate that more curved regions lead to preferential localized depositions in particle-laden drops. Furthermore, geometry induces well-defined flow structures within the drop that change according to the driving mechanism. In the case of binary mixtures, geometry dictates the spatial segregation of the more volatile component as it is depleted. Our results suggest that the drop geometry can be exploited to prescribe the particle deposition and evaporative dynamics of pure drops and the mixing characteristics of multicomponent drops, which may be of interest to a wide range of industrial and scientific applications.
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spelling mit-1721.1/1101232022-09-28T16:29:55Z Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation Wray, A. W. Che, Z. Matar, O. K. Valluri, P. Kim, J. Sefiane, K. Saenz Hervias, Pedro Javier Massachusetts Institute of Technology. Department of Mathematics Saenz Hervias, Pedro Javier The evaporation of a liquid drop on a solid substrate is a remarkably common phenomenon. Yet, the complexity of the underlying mechanisms has constrained previous studies to spherically symmetric configurations. Here we investigate well-defined, non-spherical evaporating drops of pure liquids and binary mixtures. We deduce a universal scaling law for the evaporation rate valid for any shape and demonstrate that more curved regions lead to preferential localized depositions in particle-laden drops. Furthermore, geometry induces well-defined flow structures within the drop that change according to the driving mechanism. In the case of binary mixtures, geometry dictates the spatial segregation of the more volatile component as it is depleted. Our results suggest that the drop geometry can be exploited to prescribe the particle deposition and evaporative dynamics of pure drops and the mixing characteristics of multicomponent drops, which may be of interest to a wide range of industrial and scientific applications. 2017-06-21T15:38:18Z 2017-06-21T15:38:18Z 2017-03 2016-07 Article http://purl.org/eprint/type/JournalArticle 2041-1723 http://hdl.handle.net/1721.1/110123 Sáenz, P. J.; Wray, A. W.; Che, Z.; Matar, O. K.; Valluri, P.; Kim, J. and Sefiane, K. “Dynamics and Universal Scaling Law in Geometrically-Controlled Sessile Drop Evaporation.” Nature Communications 8 (March 2017): 14783 © 2017 The Authors https://orcid.org/0000-0002-9130-3589 en_US http://dx.doi.org/10.1038/ncomms14783 Nature Communications Creative Commons Attribution 4.0 International License http://creativecommons.org/licenses/by/4.0/ application/pdf Nature Publishing Group Nature
spellingShingle Wray, A. W.
Che, Z.
Matar, O. K.
Valluri, P.
Kim, J.
Sefiane, K.
Saenz Hervias, Pedro Javier
Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title_full Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title_fullStr Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title_full_unstemmed Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title_short Dynamics and universal scaling law in geometrically-controlled sessile drop evaporation
title_sort dynamics and universal scaling law in geometrically controlled sessile drop evaporation
url http://hdl.handle.net/1721.1/110123
https://orcid.org/0000-0002-9130-3589
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